Boron doped lithium trivanadate as a cathode material for an enhanced rechargeable lithium ion batteries

Self-template processed hierarchical V2O5 nanobelts as cathode for high performance lithium ion battery

“…The corresponding to V 5+ 2p3/2 and V 5+ 2p 1/2 [45][46]. At the same time, the V 4+ peaks are also found at 515.7 eV (V 4+ 2p3/2) and 523.8 eV (V 4+ 2p1/2) [47], indicating the existence of low valence state vanadium. The relative atomic ratio of V 5+ and V 4+ is 11: 1 calculated based on the peak areas, which suggests the existence of oxygen vacancies in the lattice of V 2 O 5 to compensate the low valence ions of V 4+ [48][49].…”

Facile synthesis of mesoporous V2O5 nanosheets with superior rate capability and excellent cycling stability for lithium ion batteries

“…The peaks at 517.53 and 525.05 eV, which are attributed to the spineorbit splitting of the components, correspond to V 5þ 2p3/2 and V 5þ 2p 1/2 [49]. It is noteworthy that the V 4þ peaks are also found at 516.36 eV (V 4þ 2p3/2) and 523.80 eV (V 4þ 2p1/2) [50], indicating that the formation of low valence state vanadium. The relative atomic ratio of V 5þ and V 4þ is 9:1 calculated based on the peak areas.…”

Preparation and electrochemical properties of nanocrystalline LiBxMn2−xO4 cathode particles for Li-ion batteries by ultrasonic spray pyrolysis method

“…Feng et al [21] showed that boron doping increases the interlayer spacing of a lithium trivanadate structure and improves the structural stability during lithiation and delithiation. Also, a study on the substitution of boron in layered LiNiO 2 and LiCoO 2 structures resulted in less electrolyte decomposition [22].…”