The Li-rich layered Li 1 + x (Mn 0.6 Ni 0.2 Co 0.2 ) 1 − x O 2 (x = 0.14, 0.165, 0.19) cathode materials have been successfully synthesized through a one-pot facile co-precipitation route. The synthesized MCO 3 (M = Mn 0.6 Ni 0.2 Co 0.2 ) precursor mixing with Li 2 CO 3 was annealed at 500°C and calcinated at 900°C. The morphology and structure of the samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results indicate that the sample Li 1.165 Mn 0.501 Ni 0.167 Co 0.167 O 2 (x = 0.165) exhibits the most outstanding electrochemical performance, which may be ascribed to uniform particle size and high crystallinity. It delivers an initial discharge-specific capacity of approximately 241.7 mAh g −1 with an initial coulombic efficiency of 70.3 % at a constant density of 25 mA g −1 . A reversible dischargespecific capacity of approximately 207.2 mAh g −1 is still obtained after 100 cycles. The discharge capacities of nearly 226.8, 194.4, 158.9, 143.7, 116.8, 97.5, and 47.6 mAh g −1 can also be attained under 0.1 C, 0.2 C, 0.5 C, 1 C, 2 C, 5 C, and 10 C (1 C = 250 mA g −1 ), respectively. The Li-rich layered Li 1.165 Mn 0.501 Ni 0.167 Co 0.167 O 2 will be a promising cathode material for advanced lithium-ion batteries.