The equilibrium coexistence of sapphirine + quartz is inferred to record temperatures in excess of 980°C, based on the stability of this assemblage in the simplified chemical system FeO-MgO-Al 2 O 3 -SiO 2 (FMAS) system. However, the potential for sapphirine to contain significant Fe 3+ suggests that the stability of sapphirine + quartz could extend to lower temperatures than those constrained in this ideal system. The Wilson Lake terrane in the Grenville Province of central Labrador preserves sapphirine + quartz-bearing assemblages in highly oxidized bulk compositions, and provides an opportunity to explore the stability of sapphirine + quartz in such rock compositions within the Naallows the effect of the stability of the additional phases, biotite, K-feldspar and melt, on the stability of sapphirine + quartz to be assessed. These phase relations are evaluated generally using P-T projections, and the ultimate extension into NCKFMASHTO is done with pseudosections. Conditions of peak metamorphism in the Wilson Lake terrane are constrained using P-T pseudosections, and the appropriate H 2 O and O contents to use in the modelled compositions are investigated using T-M H2O and T-M O pseudosections. The peak P-T estimates from a sapphirine + quartz-bearing sample are 960 to 935°C at 10 to 8.6 kbar, similar to estimates from orthopyroxene + sillimanite + quartz ± garnet-bearing samples. Whereas the sapphirine + quartzbearing sample is more Fe-rich than the orthopyroxene + sillimanite-bearing sample on an all-Feas-FeO basis, once the oxidation state is taken into account, the former is effectively more magnesian than the latter, accounting for the sapphirine occurrence.