We report experimental studies of the low frequency electrodynamics of ZrB12 and Nb single crystals. AC susceptibility at frequencies 3 -1000 Hz have been measured under a dc magnetic field, H0, applied parallel to the sample surface. In the surface superconducting state for several H0 the real part of the ac magnetic susceptibility exhibits a logarithmic frequency dependence as for spin-glass systems. Kramers-Kronig analysis of the experimental data, shows large losses at ultra low frequencies (< 3 Hz). The wave function slope at the surface was found. The linear response of the order parameter to the ac excitation was extracted from the experimental data.