are self-assembled in a thermodynamically spontaneous way when chirality is about several hundreds of nanometers. LC directors are doubly twisted at this high chirality and self-assembled into a double-twisted cylinder (DTC). The way that the DTCs are stacked determines the symmetry of the BPLC structure, and the lattice length scale in common includes the visible wavelength, which appears as colorful micrographic textures. From an application perspective, a remarkable breakthrough is that polymer-stabilization method is able to extend their narrow temperature range. [6] Dispersion of nanoparticles (organic/inorganic colloids and perovskite quantum dots) or bent-core LCs and 3D confinement of BPLC like microencapsulation is also reported that it can extend the temperature range of BPs. [7][8][9][10] The polymer-stabilized BPLC (PS-BPLC) by in situ photopolymerization is a promising method not only for extending the BP temperature range but also for enhancing their electro-optic performance, such as optical isotropy, [11] selective reflection, [12] less hysteresis, [13] and fast response time. [14] Despite a successful prototyping into a PS-BPLC display, [4] the PS-BPLC has rather shown their possibility of applying to versatile photonic applications such as a diffraction grating, [15] vortex beam ] have been reported by using BPLC materials because these are advantageous for the non-mechanical beam steering. Such results support that BPLC is one of the promising materials to create such novel functional devices. However, the performance of the device is deteriorated by the multidomain structure of BPLCs. For example, the diffraction efficiency decreases significantly. Despite such importance, less attention has been paid to create and study about monodomain BPLCs for diffraction gratings among several studies previously reported. [16,[25][26][27] Some approaches report that, to resolve the unwanted multiple colors from polycrystalline lattice structure, one can adjust the chiral pitch of BPLCs and have the Bragg wavelength shifted far away from the wavelength of device operation. For instance, when the desired wavelength is within the visible region, one can control the chiral pitch to position the Bragg wavelength within UV region. However, this approach is limited to an The structural beauty of liquid crystalline blue phases is attested not only by their colorful optical micrographic textures but also by optical isotropy. More importantly, the homogeneity of the structures influences greatly to the electro-optic properties. In this work, how the lattice orientation in polymerstabilized blue phase liquid crystal (PS-BPLC) diffraction grating affects phase-modulated diffraction efficiency is elaborated. A well-arranged monodomain structure of blue phase is achieved and its diffraction capability is compared with multidomain PS-BPLC. The diffraction efficiency in the zeroth order of monodomain PS-BPLC is improved by 9% compared to that of multidomain structure. In addition, both driving and threshold voltages in m...