2014
DOI: 10.1016/j.polymdegradstab.2014.04.002
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Bridged phosphorylated diamines: Synthesis, thermal stability and flame retarding properties in epoxy resins

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Cited by 43 publications
(23 citation statements)
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“…The second route utilizes the trivalent reactant 6‐chloro‐6H‐dibenzo[c,e][1,2]oxaphosphinine (DOP‐Cl). As experienced in earlier studies, the trivalent DOP‐Cl has a higher reactivity compared to the pentavalent DOPO‐Cl, what lead to a fully substituted trivalent intermediate 11‐i . After oxidation of 11‐i , the DOPO‐substituted product 11 was gained.…”
Section: Resultsmentioning
confidence: 58%
“…The second route utilizes the trivalent reactant 6‐chloro‐6H‐dibenzo[c,e][1,2]oxaphosphinine (DOP‐Cl). As experienced in earlier studies, the trivalent DOP‐Cl has a higher reactivity compared to the pentavalent DOPO‐Cl, what lead to a fully substituted trivalent intermediate 11‐i . After oxidation of 11‐i , the DOPO‐substituted product 11 was gained.…”
Section: Resultsmentioning
confidence: 58%
“…Derivatives based on 9, 10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO) is an attractive FR. It has been reported that the DOPO‐based FRs are effective for epoxy resins , polyurethane foams , polylactic acid (PLA) , and polyamide 6 . Because the condensed phase formed in the combustion process can prevent heat and mass transfer profited from the addition of phenethyl‐bridged DOPO derivative (DiDOPO) , it can prevent heat and mass transfer profited from the addition of DiDOPO, which plays an important role in radical quenching mechanism .…”
Section: Introductionmentioning
confidence: 99%
“…In recent years, most of the researches tend to find halogen-free flame retardant solutions. Among the halogen-free systems, epoxy resin modified by phosphorus is considered as a promising alternative to halogenated flame retardants due to its low toxicity and high efficiency [9,10,14].…”
Section: Introductionmentioning
confidence: 99%