Broadband 2.9 μm emission and high energy transfer efficiency in Er3+/Dy3+ co-doped fluoroaluminate glass

Wang, Tao; Huang, Feifei; Ren, Guangyu; Cao, Wenqian; Tian, Ying; Lei, Ruoshan; Zhang, Junjie; Xu, Shiqing

doi:10.1016/j.optmat.2017.12.011

Cited by 31 publications

(7 citation statements)

References 25 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Transfer from the

^{4} I_{11 / 2}

level to

^{6} H_{5 / 2}

subsequently populates the upper dysprosium level for 3 µm emission (

^{6} H_{13 / 2}

) through effective multiphonon relaxation. Experimentally, this pathway has been investigated by few authors, though transfer is confirmed by observation of a fluorescence spectrum that is broader than that or Er 3 + alone due to the contribution from dysprosium emission at longer wavelengths . This work also generates from an extension of Dexter's theory of energy transfer an estimate for the microscopic energy transfer constant from donor to acceptor in tellurite glass,

C_{DA}

of 6.9 × 10 −38 cm 6 /s.…”

Section: Spectroscopymentioning

confidence: 68%

“…Lu 2 O 3 [33]), potentially leading to even more favourable properties. Co-doping (with Yb 3+ , Er 3+ and Tm 3+ [72][73][74][75][76][77][78][79][80][81][82][83][84][85][86]) is also an area to have received research attention, highlighting routes to enhanced 3 µm emission efficiency, although these ideas have unfortunately yet to translate into laser experiments. This is therefore an area for further study, in addition to consideration of other co-doping schemes to enhance the longer wavelength Dy 3+ 4 µm transition.…”

Section: Discussionmentioning

confidence: 99%

See 1 more Smart Citation

Dysprosium Mid‐Infrared Lasers: Current Status and Future Prospects

Woodward

Majewski

Jackson

2020

Laser & Photonics Reviews

View full text Add to dashboard Cite

With growing interest in the mid‐infrared spectral region, dysprosium has recently been revisited for efficient high‐performance infrared source development. Despite historically receiving less attention than other rare earth ions, in recent years lasers utilizing the dysprosium ion as the laser material have set record mid‐infrared performance, including tunability from 2.8 to 3:4 µm (in addition to 4:3 µm lasing), continuous wave powers exceeding 10 W, greater than 73% slope efficiencies, and even ultrafast pulsed operation. Herein, the unique energy level structure and spectroscopy of the dysprosium ion are examined and the major developments that have led to this resurgence of interest and subsequent record mid‐infrared laser performance are surveyed. Also mid‐infrared applications of emerging dysprosium lasers are highlighted, in addition to surveying the many opportunities that lie ahead.

show abstract

“…Transfer from the

^{4} I_{11 / 2}

level to

^{6} H_{5 / 2}

subsequently populates the upper dysprosium level for 3 µm emission (

^{6} H_{13 / 2}

C_{DA}

of 6.9 × 10 −38 cm 6 /s.…”

Section: Spectroscopymentioning

confidence: 68%

Section: Discussionmentioning

confidence: 99%

Dysprosium Mid‐Infrared Lasers: Current Status and Future Prospects

Woodward

Majewski

Jackson

2020

Laser & Photonics Reviews

View full text Add to dashboard Cite

show abstract

“…Using lifetime change, the Dexter and Föster formula (Eq. 2-3) can be used to quickly determine the effectiveness and likelihood (probability) of energy transfer from Nd 3+ to Er 3+ /Pr 3+ ions [ [30] , [31] , [32] ]:

In the terms of lifetime, the energy transfer probability can be expressed by Refs. [ 33 , 34 ]:

where τ Nd_co-doped is the sensitizer's lifetime in the presence of activators (Er 3+ /Pr 3+ ) and τ Nd-pure is intrinsic decay time of sensitizer (Nd 3+ ) in the absence of activators.…”

Section: Resultsmentioning

confidence: 99%

Luminescence properties and energy transfer of Nd3+- Er3+/ Nd3+-Pr3+ co-doped LFP glasses system

Rajagukguk,

Panggabean,

Sarumaha

et al. 2023

Heliyon

View full text Add to dashboard Cite

“…The changing of lifetime revealed a process of Eu 2+ → Eu 3+ energy-transfer effect existing in the nanohybrid SiO 2 –(Eu 2+ , Eu 3+ )–HPBA. And the energy-transfer efficiency (η) can be estimated by the equation listed below where τ 0 and τ were the measured lifetimes of Eu 2+ in SiO 2 –Eu 2+ –HPBA and SiO 2 –(Eu 2+ , Eu 3+ )–HPBA, respectively.…”

Section: Resultsmentioning

confidence: 99%

Eu²⁺/Eu³⁺-Based Smart Duplicate Responsive Stimuli and Time-gated Nanohybrid for Optical Recording and Encryption

Feng

Kong

Yang

et al. 2018

ACS Appl. Mater. Interfaces

View full text Add to dashboard Cite

With the rapid development of information science, it is urgent that memory devices possessing high security, density, and desirable storage ability should be developed. In this work, a smart duplicate response of stimuli has been developed and a time-gate nanohybrid based on variable valence Eu 2+ /Eu 3+ coencapsulated has been fabricated and acts as active material in the multilevel and multidimensional memory devices. The luminescence lifetime of Eu 3+ in this nanohybrid gave a stimuli response due to which the energy level of the coordinated ligand could be modulated. Furthermore, by a simple sintering procedure, Eu 3+ was partially in situ reduced to Eu 2+ with a short lifetime in the system. And the in situ reduction ensured both Eu 3+ and Eu 2+ ions' uniform distribution in the nanohybrid and simultaneous response upon light excitation of variable valence Eu ions. Interestingly, Eu 3+ revealed a prolonged lifetime because of the presence of an energy-transfer effect of Eu 2+ → Eu 3+ . Such a nanohybrid had abundant luminescent properties, including the short lifetime of Eu 2+ , the energy transfer from the Eu 2+ to Eu 3+ ions, and the stimuli response of the Eu 3+ lifetimes when exposed to acidic or basic vapor, thus giving birth to interesting recording and encryption performance in spatial−temporal dimensions. We believe that this research will point out a new direction for the future development of multilevel and multidimensional optical recording and encryption materials.

show abstract

Broadband 2.9 μm emission and high energy transfer efficiency in Er3+/Dy3+ co-doped fluoroaluminate glass

Cited by 31 publications

References 25 publications

Dysprosium Mid‐Infrared Lasers: Current Status and Future Prospects

Dysprosium Mid‐Infrared Lasers: Current Status and Future Prospects

Luminescence properties and energy transfer of Nd3+- Er3+/ Nd3+-Pr3+ co-doped LFP glasses system

Eu²⁺/Eu³⁺-Based Smart Duplicate Responsive Stimuli and Time-gated Nanohybrid for Optical Recording and Encryption

Contact Info

Product

Resources

About

Broadband 2.9 μm emission and high energy transfer efficiency in Er3+/Dy3+ co-doped fluoroaluminate glass

Cited by 31 publications

References 25 publications

Dysprosium Mid‐Infrared Lasers: Current Status and Future Prospects

Dysprosium Mid‐Infrared Lasers: Current Status and Future Prospects

Luminescence properties and energy transfer of Nd3+- Er3+/ Nd3+-Pr3+ co-doped LFP glasses system

Eu2+/Eu3+-Based Smart Duplicate Responsive Stimuli and Time-gated Nanohybrid for Optical Recording and Encryption

Contact Info

Product

Resources

About

Eu²⁺/Eu³⁺-Based Smart Duplicate Responsive Stimuli and Time-gated Nanohybrid for Optical Recording and Encryption