Building up 3-D framework structure from interlinking layered cobalt phosphates and organic pillars

Synthesis and structural characterization of two cobalt phosphites: 1-D (H3NC6H4NH3)Co(HPO3)2 and 2-D (NH4)2Co2(HPo3)3

“…However, cobalt has high coordination flexibility and a strong tendency to form edge-sharing or face-sharing linkages of metal-oxygen polyhedra. These properties usually lead to difficulty in mimicking a zeolitetype structure, but can lead to the possibility of new structural morphology and interesting magnetic properties [3][4][5][6][7][8]. Recently, the HPO 3 group has been investigated as a possible replacement for the tetrahedral HPO 4 unit with great success [9][10][11][12][13][14].…”

Syntheses, structures and magnetic properties of two new one-dimensional cobalt (II) phosphites with organic amines acting as ligands

“…To date, a number of studies on inorganic-organic hybrid phosphates/phosphites of various transition metals such as Fe [11][12][13][14], Cr [8,15], V [15][16][17][18][19][20], Mn [21][22][23] and Zn [24][25][26][27][28][29][30][31][32] have been carried out under hydro/solvothermal conditions. Moreover, there is also some attention to open-framework inorganic-organic hybrid cobalt phosphates and phosphites [33][34][35][36][37][38][39][40][41], which are obtained by the combination of the oxalate and phosphate/ phosphite groups in the same crystalline material or based on organonitrogen ligands and phosphate/phosphite groups. In order to extend the knowledge about the inorganic-organic hybrid phosphites, we decide to focus our attention on the Co(II) phophites system with organic amines as ligands.…”

Synthesis, crystal structure, physical and catalytic oxidation studies of a new hybrid phosphate [(N2H5)2Co(HPO4)2]

“…As shown in Fig. 2 [25]. The square planar arrangement around the Co atom is slightly distorted, with O2−Co−O2 i and O3-Co-O3 i angles both of 180.0(5)° (Table 3).…”