2010
DOI: 10.1016/j.cap.2009.07.018
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Bulk crystal growth and characterization of non-linear optical bisthiourea zinc chloride single crystal by unidirectional growth method

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Cited by 75 publications
(40 citation statements)
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“…The specimen crystallizes with centrosymmetric space group Pnma and refined to a low R value of 0.0176 (final R indices). This analysis clearly indicates that the incorporation of Fe 3+ in BTZC leads to change the space group from noncentrosymmetric (Pn2 1 a) [26] to centrosymmetric (Pnma) which in turn enforced to predict the loss of second harmonic generation. However, the prediction could not be found true as some weak SHG was found as observed in the forthcoming NLO studies.…”
Section: X-ray Analysis For Crystal Structure and Perfectionmentioning
confidence: 91%
“…The specimen crystallizes with centrosymmetric space group Pnma and refined to a low R value of 0.0176 (final R indices). This analysis clearly indicates that the incorporation of Fe 3+ in BTZC leads to change the space group from noncentrosymmetric (Pn2 1 a) [26] to centrosymmetric (Pnma) which in turn enforced to predict the loss of second harmonic generation. However, the prediction could not be found true as some weak SHG was found as observed in the forthcoming NLO studies.…”
Section: X-ray Analysis For Crystal Structure and Perfectionmentioning
confidence: 91%
“…The growth setup used here is a modified version of the Sankaranarayanan-Ramasamy (SR) method, which is somewhat similar to our earlier, reported one [16]. The assembly was optimized in such a way as to obtain a maximum temperature profile at the top.…”
Section: Growth Assembly and Crystal Growthmentioning
confidence: 98%
“…In exacting, the peak intensity of 3458 cm -1 is very strong for Pd (0.3 mol %) doped KAP when compared to the peaks 3449 cm -1 and 3441 cm -1 for Pd (0.1 & 0.2 mol %) doped KAP respectively. The difference in sharpness of multiple bands in this region may also be taken as evidence for the doping of divalent metal ions Measurement of hardness is a useful nondestructive testing method to determine the hardness of the material [13]. Vickers microhardness test was carried out on pure and Pd doped KAP single crystals using microhardness tester flitted with a diamond indenter.…”
Section: Ftir Analysesmentioning
confidence: 99%