“…For example, iridescence, [ 3 ] non‐iridescence, [ 4 ] mixed [ 5 ] or dynamic [ 6 ] colors, chirality, [ 7 ] polarization, [ 8 ] ultra‐blackness, [ 9 ] or other optical effects [ 10 ] derived from these multi‐scale nanomaterials, and are important for camouflage, mating, warning, signaling, or thermoregulation of the creatures. [ 8,11 ] Inspired by these fascinating photonic structures, great efforts have been devoted to mimicking the micro‐/nano‐architectures to realize corresponding optical properties or functions, [ 10c,11b,12 ] which have spurred the development of next‐generation photonic sensors, [ 13 ] displays, [ 13b,14 ] and photovoltaics. [ 15 ] In particular, hierarchical photonic superstructures (HPSs) with multiple optical elements [ 12f,13 b, 15a,16 ] provide delicate optical features derived from collective optical functions, which could be precisely engineered by variations of the physical parameters at the nanoscale, and therefore are of great potential for highly secure anti‐counterfeiting.…”