[C6H14N]PbI3: a one-dimensional perovskite-like order–disorder phase transition material with semiconducting and switchable dielectric attributes

Replacing methylammonium (MA+), formamidine (FA+), and/or cesium (Cs+) in 3D metal halide perovskites by larger organic cations have built a series of low‐dimensional metal halide perovskites (LDMHPs) in which the inorganic metal halide octahedra arranging in the forms of 2D layers, 1D chains, and 0D points. These LDMHPs exhibit significantly different optoelectronic properties from 3D metal halide perovskites (MHPs) due to their unique quantum confinement effects and large exciton binding energies. In particular, LDMHPs often have excellent broadband luminescence from self‐trapped excitons. Chemical composition, hydrogen bonding, and external factors (temperature and pressure etc.) determine structures and influence photoelectric properties of LDMHPs greatly, and especially it seems that there is no definite regulation to predict the structure and photoelectric properties when a random cation, metal, and halide is chosen to design a LDMHP. Therefore, this review discusses the construction strategies of the recent reported LDMHPs and their application progress in the luminescence field for a better understanding of these factors and a prospect for LDMHPs’ development in the future.

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Section: Structure Construction and Luminescence Performancementioning

confidence: 99%

Low‐Dimensional Metal Halide Perovskite Crystal Materials: Structure Strategies and Luminescence Applications

2021

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“…Our work provides novel insights into the correlation of structural and optical properties in layered double perovskites and demonstrates how the proper selection of the organic cations can be used to avoid or deliberately trigger phase transitions, with application in devices for improved thermal stability 14 or exploiting switching behavior. 29 …”

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confidence: 99%

Phase Transitions in Low-Dimensional Layered Double Perovskites: The Role of the Organic Moieties

Martín‐García

Spirito

Biffi

et al. 2020

J. Phys. Chem. Lett.

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Halide double perovskites are an interesting alternative to Pb-containing counterparts as active materials in optoelectronic devices. Low-dimensional double perovskites are fabricated by introducing large organic cations, resulting in organic/inorganic architectures with one or more inorganic octahedra layers separated by organic cations. Here, we synthesized layered double perovskites based on 3D Cs 2 AgBiBr 6 , consisting of double (2L) or single (1L) inorganic octahedra layers, using ammonium cations of different sizes and chemical structures. Temperature-dependent Raman spectroscopy revealed phase transition signatures in both inorganic lattice and organic moieties by detecting variations in their vibrational modes. Changes in the conformational arrangement of the organic cations to an ordered state coincided with a phase transition in the 1L systems with the shortest ammonium moieties. Significant changes of photoluminescence intensity observed around the transition temperature suggest that optical properties may be affected by the octahedral tilts emerging at the phase transition.

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“…(H 2 dabco‐C 2 H 5 )[ZnCl 4 ] and (H 2 dabco‐C 2 H 5 )[CoCl 4 ] undergo reversible phase transformations at 245 K and 261 K, respectively . The structural phase transition of 1‐methylpiperidinium triiodoplumbate(II) (MPIP) happens at the temperature of T c =202 K . With 1‐(cyclopentyl)‐4‐aza‐1‐azonia‐bicyclo[2.2.2]octane as organic component, organic‐inorganic hybrid compound, C 11 H 22 Cl 4 MnN 2 undergoes reversible solid‐state phase transition at 170 K …”

Section: Introductionmentioning

confidence: 55%

A Semiconducting Organic‐Inorganic Hybrid Metal Halide [(C₆H₁₅ClNO)₂CdBr₄] with Switchable Dielectric and Large Phase Transition Thermal Hysteresis

et al. 2019

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A semiconducting organic-inorganic hybrid compound [(C 6 H 15 ClNO) 2 CdBr 4 ] (1), which displays excellent switchable dielectric, has been successfully synthesized. Systematic characterizations including variable-temperature structural analyses, DSC, TG, variable-temperature dielectric measurements, solidstate UV/Vis diffuse reflectance and photoluminescence were performed. DSC curve shows a couple of reversible heat anomaly peaks at 363/322 K on the heating/cooling process with a very large thermal hysteresis of ∼ 41 K, indicating the first-order type of phase transition. Obvious dielectric switching occurs at about 364 K and 314 K also with a large thermal hysteresis of ∼ 50 K in the heating and cooling process, respectively. The large phase transition thermal hysteresis makes 1 a potential latent heat based thermal energy storage materials which can maintain the system over a wide temperature range. Variable-temperature structural analyses show that the rotating or orientating movement of anion clusters is the mainly attribution for the phase transition of 1.

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[C₆H₁₄N]PbI₃: a one-dimensional perovskite-like order–disorder phase transition material with semiconducting and switchable dielectric attributes

Abstract: Here we report a new one-dimensional organic–inorganic hybrid, adopting an ABX3 perovskite-like architecture, which exhibits semiconducting and switchable dielectric attributes.

Cited by 50 publications

References 60 publications

Low‐Dimensional Metal Halide Perovskite Crystal Materials: Structure Strategies and Luminescence Applications

Low‐Dimensional Metal Halide Perovskite Crystal Materials: Structure Strategies and Luminescence Applications

Phase Transitions in Low-Dimensional Layered Double Perovskites: The Role of the Organic Moieties

A Semiconducting Organic‐Inorganic Hybrid Metal Halide [(C₆H₁₅ClNO)₂CdBr₄] with Switchable Dielectric and Large Phase Transition Thermal Hysteresis

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[C6H14N]PbI3: a one-dimensional perovskite-like order–disorder phase transition material with semiconducting and switchable dielectric attributes

Abstract: Here we report a new one-dimensional organic–inorganic hybrid, adopting an ABX3 perovskite-like architecture, which exhibits semiconducting and switchable dielectric attributes.

Cited by 50 publications

References 60 publications

Low‐Dimensional Metal Halide Perovskite Crystal Materials: Structure Strategies and Luminescence Applications

Low‐Dimensional Metal Halide Perovskite Crystal Materials: Structure Strategies and Luminescence Applications

Phase Transitions in Low-Dimensional Layered Double Perovskites: The Role of the Organic Moieties

A Semiconducting Organic‐Inorganic Hybrid Metal Halide [(C6H15ClNO)2CdBr4] with Switchable Dielectric and Large Phase Transition Thermal Hysteresis

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Product

Resources

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[C₆H₁₄N]PbI₃: a one-dimensional perovskite-like order–disorder phase transition material with semiconducting and switchable dielectric attributes

A Semiconducting Organic‐Inorganic Hybrid Metal Halide [(C₆H₁₅ClNO)₂CdBr₄] with Switchable Dielectric and Large Phase Transition Thermal Hysteresis