CdS thin films have been deposited on Transparent Conducting Oxide (TCO, containing SnO2: F) coated glass substrates from aqueous sodium thiosulfate solutions, using the galvanic technique. A cadmium foil was used as a sacrificial anode and was the only source of Cd++ ions for CdS thin films, no external bias being used during film depositions. The films have been characterized using X‐ray diffraction, SEM, EDX, AFM and optical absorption studies. AAS analyses were carried out to determine the Cd content in solutions after film deposition. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)