2008
DOI: 10.1021/cr0782574
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Calcium Orthophosphates: Crystallization and Dissolution

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Cited by 861 publications
(796 citation statements)
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References 395 publications
(1,253 reference statements)
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“…58,59 That OCP can act as an intermediate between ACP and HAP during bone formation has also been widely discussed, but remains controversial. 36,60 In its support, the so-called central dark line observed by TEM in biogenic HAP has been attributed to a central OCP occlusion which may derive from the lattice mismatch between OCP and HAP. 61,62 OCP has also been observed in the forming cranial suture of a mouse using Raman spectroscopy, where it is notable that these samples were characterised without dehydration.…”
Section: Discussionmentioning
confidence: 96%
See 1 more Smart Citation
“…58,59 That OCP can act as an intermediate between ACP and HAP during bone formation has also been widely discussed, but remains controversial. 36,60 In its support, the so-called central dark line observed by TEM in biogenic HAP has been attributed to a central OCP occlusion which may derive from the lattice mismatch between OCP and HAP. 61,62 OCP has also been observed in the forming cranial suture of a mouse using Raman spectroscopy, where it is notable that these samples were characterised without dehydration.…”
Section: Discussionmentioning
confidence: 96%
“…36 Study of the transformation of OCP to HAP has suggested that this can occur either by a dissolution/ reprecipitation mechanism or by a solid-state transformation in which hydrolysis of an OCP unit cell leads to a layer of HAP two units cells thick. 36 ACP, in turn, is unstable in solution and its lifetime varies according to the presence of additives, the solution composition, pH and temperature. 49 A recent detailed study of the mechanism of CaP precipitation in solutions supersaturated with HAP has shown that this process is based on the aggregation of calcium triphosphate complexes.…”
Section: Discussionmentioning
confidence: 99%
“…10,11 Amorphous calcium orthophosphates (ACP) have also been widely studied, although their involvement in biomineralisation processes in mammals is still the subject of much controversy. While there is no irrefutable proof of the involvement of ACP as a precursor to hard tissue, increasing evidence is now being reported to support this supposition and the reader is directed to the literature for a more detailed discussion (see, for example, studies by Rey et al 12 or Nancollas et al 13 for further details). It is conceivable therefore that synthetic amorphous inorganic materials may offer a useful route to hard tissue replacement.…”
Section: Introductionmentioning
confidence: 99%
“…In the case of gypsum, the structural similarity with brushite and pharmacolite CaHAsO 4 . 2H 2 O was considered in depth by Heijnen and Hartman 18 , who presented a comparative study of their crystal morphologies using an A-setting for the three unit cells. More recent papers [19][20][21][22] illustrates how this structural similarity favors the development of oriented intergrowths between these three minerals.…”
Section: Introductionmentioning
confidence: 99%
“…2H 2 The present study explores the mixing properties of the Ca(SO 4 ,HPO 4 ) . 2H 2 O solid solution and the role of the "double-salt" Ca 2 SO 4 HPO 4 ·4H 2 O (ardealite) by means of precipitation experiments carried out in a solution calorimeter at 25ºC.…”
mentioning
confidence: 99%