Calibration method for the infrared-spectrometric trace gas analysis

Heise, H. M.; Kirchner, Herbert; Richter, Wolfgang

doi:10.1007/bf00481190

Cited by 12 publications

(1 citation statement)

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“…Several groups are working in this field; recent activities were reported in the literature. 35,36 Within our project the collection of highly resolved reference data with a maximum spectral resolution of 0.2 cm Ϫ1 has been an important task. It is necessary that all original interferograms be saved electronically, because the storage of the basic data is essential to allow the implementation of novel data treatment, as illustrated in this work.…”

Section: Resultsmentioning

confidence: 99%

Improved strategies for quantitative evaluation of atmospheric FTIR spectra obtained in open-path monitoring

Mller¹,

Heise²,

Mosebach

et al. 1999

Field Analyt. Chem. Technol.

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Improvements in the quantitative evaluation of atmospheric Fourier‐transform infrared (FTIR) spectra, obtained in environmental monitoring by using a bistatic spectrometer setup, are presented. Preprocessing of interferograms and spectral data was carried out to improve the photometric accuracy and wave‐number scale reproducibility, necessary for reliable quantitative analysis. Univariate component analysis was optimized, and a refined strategy for multivariate analysis by least squares was set up. Special procedures were developed for the determination of benzene and of small molecules with resolved rotation–vibration fine structure. Results from field measurements, which were obtained by using the implemented subroutines for univariate and multivariate spectrum evaluation, are presented and discussed. © 1999 John Wiley & Sons, Inc. Field Analyt Chem Technol 3: 141–159, 1999

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Section: Resultsmentioning

confidence: 99%

Improved strategies for quantitative evaluation of atmospheric FTIR spectra obtained in open-path monitoring

Mller¹,

Heise²,

Mosebach

et al. 1999

Field Analyt. Chem. Technol.

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Automotive Emissions Analysis with Spectroscopic Techniques

Hirschberger

2000

Encyclopedia of Analytical Chemistry

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Quantitative analysis of automotive emissions gives detailed information about a motor's combustion behavior and gives information about the contribution from traffic to air pollution. Following the introduction, which discusses the problems of exhaust gas analysis, section 2 covers the basics of the physical effects, that the different spectroscopic systems are based on. These physical effects are discussed especially with respect to gas analysis. Section 3 describes the functioning of different spectroscopic systems, the measuring procedures and different examples of exhaust gas analysis. Simple examples are used to illustrate the functioning of Fourier transform infrared (FTIR) and diode laser (DL) systems. The construction of a completely home‐made Raman polychromator is described in detail. Specific problem areas are pointed out. Selected examples of exhaust gas analysis show typical applications of the particular methods. Section 4 discusses the present and future potential of the systems described.

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Substanzpräparation

2003

IR‐Spektroskopie

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Calibration method for the infrared-spectrometric trace gas analysis

Cited by 12 publications

References 11 publications

Improved strategies for quantitative evaluation of atmospheric FTIR spectra obtained in open-path monitoring

Improved strategies for quantitative evaluation of atmospheric FTIR spectra obtained in open-path monitoring

Automotive Emissions Analysis with Spectroscopic Techniques

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