Chefs and other food preparation workers are at a high risk of scald injuries from hot liquids. Chefs’ clothing has the potential to act as a protective barrier between the skin and the thermal hazard. Although, impermeable barriers coupled with an insulating layer of fabric tend to offer the greatest protection against hot liquid penetration, the potential for heat strain and discomfort to workers may make them impractical in the kitchen environment. This study examined the effects of common finishing treatments used in chef jacket fabrics and the impact of layers on the protection offered against hot water burn injuries. The Teflon® treated fabrics offering combined stain and water repellency, provided the greatest protection with the lowest absorbed energy and longest times to second degree burn injury compared with the other finishes (i.e., regular, water repellent and soil release). Findings also showed that in most cases, increasing the number of layers improved protection provided by the fabric systems, with the Teflon® finished fabrics providing the highest protection against scald injuries as fabric layers increased.