The rapid expansion of impermeable surfaces in cities has a major impact on urban hydrology by reducing rainwater infiltration and increasing runoff rates and peaks. The use of urban trees as stormwater management tools is gaining recognition for their potential to mitigate flood risk and provide additional ecosystem services. We conducted an in‐situ field experiment to measure throughfall on Norway maple (Acer platanoides) and small‐leaved lime (Tilia cordata) to assess the interception capacity of solitary urban trees under different degrees of surface sealing in the city of Freiburg, Germany. We examined the relationships between rainfall characteristics, tree morphological traits, and the interception behaviour, analysing eight trees per species over 76 recorded rainfall events from April to September 2021. Average interception values were higher for small‐leaved lime trees (70.3% ± 6.6%) than for Norway maple (54.8% ± 10.3%) surpassing those in typical forested environments. The average interception loss of all recorded events was 2.6 ± 0.6 mm for Norway maple and 3.7 ± 0.3 mm for small‐leaved lime. For both tree species, significant linear correlations were found between the relative interception and factors such as rainfall depths, the leaf area index (LAI), and the plant area index (PAI) (adj. R2 >0.45). Unlike Norway maple, small‐leaved lime demonstrated significant relationships between several tree morphological parameters and interception (adj. R2 >0.43). The LAI of both species significantly decreased with the increasing degree of surface sealing, which in turn affected interception rates. Our results enhance the understanding of the interception process by solitary trees in urban contexts and enables the parameterization of interception rates using measurable properties. To develop a comprehensive database for modelling parameters and aid urban planners in stormwater management, further field experiments involving various tree species are essential.