Single-wall carbon nanotubes (SWCNTs) with excellent physicochemical properties are considered a promising candidate for the electrical and mechanical reinforcements of polymers. However, the poor dispersion of SWCNTs in plastics seriously limits their application and the performance enhancement achieved. Here we coat free-standing, highly conductive SWCNT film onto the surface of polyethylene terephthalate (PET) film by a hot-pressing method. Due to the uniform SWCNT network structure and strong interfacial interaction, the SWCNT/PET hybrid film showed notably enhanced electrical and mechanical properties even though with a very low SWCNT weight fraction of 0.066%. The surface square resistance of the SWCNT/PET film decreased to 120-140 Ω/□ from 1016Ω/□. In addition, the Young's modulus and tensile strength of the SWCNT/PET film reached 4.6 GPa and 148 MPa, which are 31.3% and 24.4%, respectively, higher than pure PET film. The SWCNT/PET film shows excellent mechanical durability and thermal stability, demonstrating their potential use as an antistatic material.