Abstract. Fibre-reinforced ceramics have a higher fracture toughness compared to monolithic ceramics. Therefore, they are an attractive material for lightweight structural components in high-temperature applications. The liquid-silicon infiltration (LSI) process is a cost-efficient manufacturing route for fibre-reinforced ceramics consisting of three processing steps. A carbon-fibre-reinforced plastic (CFRP) composite is fabricated, which is converted in a porous C/C composite by pyrolysis. Liquid silicon is infiltrated to form a dense C/C-SiC composite. The performance of the composites strongly depends on the raw materials. The matrix chemistry in particular plays a key role in developing composites with tailored functional properties. The aim of this work is to investigate the mechanical properties and the failure behaviour of CFRP, C/C and C/C-SiC composites in dependence on the matrix chemistry. The composites are fabricated by the liquid-silicon infiltration process. Different phenolic resins as matrix polymers are used. The mechanical properties are characterized by bending tests and the failure behaviour is observed in-situ. Additionally, microstructural and fractrographic analyses are done. It can be shown that the formation of the microstructure and therefore the mechanical properties and the failure behaviour are strongly influenced by the matrix chemistry over all processing steps.