2017
DOI: 10.1021/acscatal.7b02577
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Carbon-Increasing Catalytic Strategies for Upgrading Biomass into Energy-Intensive Fuels and Chemicals

Abstract: Lignocellulosic biomass is the most abundant organic carbon source and has received a great deal of interest as renewable and sustainable feedstock for the production of potential biofuels and value-added chemicals with a wide range of designed catalytic systems. However, those natural polymeric materials are composed of short-chain monomers (typically C6 and C5 sugars) and complex lignin molecules containing plenty of oxygen, resulting in products during the downstream processing having low-grade fuel propert… Show more

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Cited by 300 publications
(163 citation statements)
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“…After analyzing the chemical structure of the biomass‐derived molecules, we planned to develop the old Michael addition reaction for the new purpose of synthesizing high‐density jet and diesel fuels. Glucose and xylose are the main building blocks of terrestrial biomass that can be upgraded to a variety of biomass‐derived chemicals with C═C double bonds and carbonyl groups . These chemicals are potential Michael donors and Michael acceptors.…”
Section: Optimization Studiesmentioning
confidence: 99%
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“…After analyzing the chemical structure of the biomass‐derived molecules, we planned to develop the old Michael addition reaction for the new purpose of synthesizing high‐density jet and diesel fuels. Glucose and xylose are the main building blocks of terrestrial biomass that can be upgraded to a variety of biomass‐derived chemicals with C═C double bonds and carbonyl groups . These chemicals are potential Michael donors and Michael acceptors.…”
Section: Optimization Studiesmentioning
confidence: 99%
“…With optimized reaction conditions (Table , entry 9), the substrate scope of this TBAB/K 3 PO 4 ·3H 2 O catalytic solvent‐free Michael addition reaction with respect to Michael donors ( 1a – 1d ) and Michael acceptors ( 2a–2d ) was investigated. The Michael acceptors and donors were obtained from the small molecules derived from terrestrial biomass . For example, 1a can be obtained by simple esterification of malonic acid with ethanol; 2a, 2b, 2c, and 2d can be obtained by the esterification of acrylic acid with related alcohols.…”
Section: Optimization Studiesmentioning
confidence: 99%
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“…The ongoing exhaustion of non‐renewable fossil resources and corresponding environmental concerns caused by their continuously growing consumption have urged developing new technologies to utilize renewable and green resources . Biomass, as the largest renewable carbon pool on earth, is anticipated to play a crucial role for a sustainable supply of energy and chemicals . Thus tremendous efforts have been set forth to develop novel technologies for the conversion of biomass to valuable chemicals .…”
Section: Introductionmentioning
confidence: 99%