Valorisation of CaCO 3 -containing solid wastes for H 2 S removal from the gas phase.• Design of a triphasic gas/liquid/solid process.• Crucial importance of H 2 S dissolution and dissociation steps in CaCO 3 suspension.• Oxidation of dissolved sulfur species into stable sulfite, sulfate, and thiosulfate.• Understanding of the mechanism of H 2 S removal by this triphasic process.