Organic petrology and geochemical studies (Rock-Eval/TOC) were carried out on shales from the Besa River (Upper Devonian-Lower Carboniferous), Yohin, Clausen, Prophet, Golata, and Manson Formations (Lower Carboniferous) in exposed sequences at Jackjish Gap-Yohin Ridge and in a subsurface section in the North Beaver River area of the Liard Basin. Basinal shales of the Besa River Fm. have TOC values ranging from I to 4% and contain abundant type 11, dominantly amorphous, kerogen of marine origin. Shales in the Yohin Fm. (slope to neritic shelf), Clausen Fm. (basin and slope deposits), Prophet Fm. (carbonate slope), and Golata Formations are of mixed marine and terrestrial origins and yield TOC values of I to 3%. Kerogen in the Golata @rodelta shales) and Yohin Formations are dominated by terrestrial components, while the Clausen and Hen kerogen comprises marine liptinites and bitumens. Kerogen from the deltaic Matfson shales at Jackfish Gap are types I1 and Ill, having mired marine and terrestrial origins consistent with shallow. nearshore, subtidal environments. m e coals, which are rich in inertinite and liptinite (up to 30%), are sapropelic and probably lacustrine in origin. Algal laminites associated with coals in the Upper Manson have > 10% TOC values, while non-laminite shales contain between 2 and 5 % TOC. Comparable measured and calculated vitrinite reflectance data indicate that kerogen in the Lower Carboniferous at Jackjish Gap is mature (0.5-1. I %). Kerogen in correlative formations in the subsurface at Nonh Beaver River is more marine. Vitrinites are rare and oxidized, but four populations of bituEnergy Sources 1993.15:289-314.290 J. Potter et al. mens are distinguished on the basis of relative reflectivity and morphological or petrophysical associations. Types A and B bitumens are primary and by-products of hydrocarbon generation from type II (algal and amorphous) kerogens. Correlations between depth and reflectance of bitumens A and B are very good (? -0.97%).Vitrinite reflectance data calculated from bitumen reflectance measurements for the Besa River (1.6-2.1%), Prophet (1.5%). and Golata (1.2%) indicate that they are potential sources of catagenic gas. nte Mattson kerogen is mature (0.84-1.0% VRJ, oil and gas-prone.