Using first-principles calculations, we study tunneling properties and electronic structures of Si(001)/SiO 2 /Si(001) junctions in a wide energy range covering the local energy gap in the SiO 2 regions. We show that the tunneling spectra T (E) as functions of energy E have overall similarity to the projected densities of states (PDOS) at the centers of the SiO 2 regions, but T (E) and PDOS have significant difference in their dependencies on the SiO 2 thickness. From the energy dependencies of T (E) and PDOS, distinctive energy ranges are recognized in the valence and conduction bands, reflecting the local electronic structures in the SiO 2 region induced from the Si regions. From the difference in the SiO 2-thickness dependencies of T (E) and PDOS and from eigenchannel analysis, we find that the tunneling wave function inside the SiO 2 region decreases with a decay rate which itself decreases as the tunneling distance increases, resulting in a smaller averaged decay rate per length for a thicker SiO 2 region. These results provide a rich picture for the SiO 2 barrier in the aspects of tunneling and local electronic structures, and a theoretical framework generally applicable to other tunneling barriers.