2016
DOI: 10.1016/j.cattod.2015.12.017
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Catalytic activity of LiZr2(PO4)3 nasicon-type phosphates in ethanol conversion process in conventional and membrane reactors

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Cited by 22 publications
(5 citation statements)
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“…25,26 The LATP crystal has both Lewis acidic sites (metal ions) and Brönsted basic sites (PO 4 3À groups and oxygen ions). 27 Consequently, the ethanol derivatives are produced on the activated LATP surface during the high-energy milling. Although furan is potentially derived from the cyclization of diethyl ether and the subsequent dehydrogenation reaction, it is difficult to analyze side reactions of the solvent under milling.…”
Section: Preparation and Characterization Of Ultrane A-latp Powdermentioning
confidence: 99%
“…25,26 The LATP crystal has both Lewis acidic sites (metal ions) and Brönsted basic sites (PO 4 3À groups and oxygen ions). 27 Consequently, the ethanol derivatives are produced on the activated LATP surface during the high-energy milling. Although furan is potentially derived from the cyclization of diethyl ether and the subsequent dehydrogenation reaction, it is difficult to analyze side reactions of the solvent under milling.…”
Section: Preparation and Characterization Of Ultrane A-latp Powdermentioning
confidence: 99%
“…Shifting the equilibrium limit by continuous hydrogen removal was reported for the dehydrogenation of ethanol with a Pd−Ru alloy Li 1.1 Zr 1.9 In 0.1 (PO 4 ) 3 CM . Modelling ethane dehydrogenation with a Pd−Ag membrane indicated that reduced energy costs and enhanced reaction yields would be possible .…”
Section: Catalytic Membranes (Cms)mentioning
confidence: 99%
“…These materials, composed of transition metal ions intimately linked to phosphorus groups, exhibit intriguing electronic, 1–3 magnetic, 4,5 optical, 6,7 and catalytic behaviors. 8–10 A thorough understanding of the crystal structures of transition metal phosphates is essential for unlocking their distinctive physical properties.…”
Section: Introductionmentioning
confidence: 99%