Catalytic oxidation and capture of elemental mercury from simulated flue gas using Mn-doped titanium dioxide

Zhi, Jingtao; Yu, Xianqun; Bao, Jianchun; Jiang, Xiaoxiang; Yang, Hongmin

doi:10.1007/s11814-016-0026-5

Cited by 8 publications

(1 citation statement)

References 35 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…6, we find that SO 2 inhibited mercury removal, and that was consistent with the conclusion of Zhi et al. 37 From Fig. 6, the addition of 8% H 2 O and 15% H 2 O reduced the Hg 0 breakthrough rate compared with that without H 2 O in O 2 /CO 2 /SO 2 .…”

Section: The Addition Of So 2 On Hg 0 Breakthrough Rate With Differensupporting

confidence: 90%

Synergistic effect between H₂O and SO₂ on mercury removal by activated carbon in O₂/CO₂ conditions

Wang

Shen

Duan

et al. 2018

J of Chemical Tech & Biotech

View full text Add to dashboard Cite

BACKGROUND This work evaluated the mechanism of H2O on mercury oxidation and adsorption by activated carbon in simulated flue gas in a fixed‐bed reactor. The effect of the addition of SO2 on the mercury removal was also discussed. Mercury desorption tests were conducted in a setup for classifying mercury forms adsorbed on activated carbon by the temperature‐programmed desorption (TPD) method. RESULTS The results indicated that H2O could inhibit Hg0 removal through blocking the microporous channels of activated carbon. Additionally, the enriched H2O could provide the electrons to inhibit Hg0 oxidation. While medium H2O concentrations around 15% could dominate the competitive adsorption in O2/CO2, high and low H2O concentrations of 23% and 8%, respectivly, could not dominate the competition. CONCLUSION With the addition of SO2 in O2/CO2, Hg0 removal efficiency decreased with H2O increased from 8% to 23%. Furthermore, Hg0 adsorption proportion were all larger than 87% with the addition of SO2 with H2O in O2/CO2, which indicated that Hg0 adsorption was the main contributor to Hg0 removal performance. These results are useful for the control of mercury in O2/CO2 combustion technology. © 2018 Society of Chemical Industry

show abstract

Section: The Addition Of So 2 On Hg 0 Breakthrough Rate With Differensupporting

confidence: 90%

Synergistic effect between H₂O and SO₂ on mercury removal by activated carbon in O₂/CO₂ conditions

Wang

Shen

Duan

et al. 2018

J of Chemical Tech & Biotech

View full text Add to dashboard Cite

show abstract

A study on simultaneous catalytic ozonation of Hg0 and NO using Mn–TiO2 catalyst at low flue gas temperatures

et al. 2018

View full text Add to dashboard Cite

Experimental solubility and absorption mechanism of dilute SO2 in aqueous diethylene glycol dimethyl ether solution

Xiao

Wei

2016

Korean J. Chem. Eng.

View full text Add to dashboard Cite

Catalytic oxidation and capture of elemental mercury from simulated flue gas using Mn-doped titanium dioxide

Cited by 8 publications

References 35 publications

Synergistic effect between H₂O and SO₂ on mercury removal by activated carbon in O₂/CO₂ conditions

Synergistic effect between H₂O and SO₂ on mercury removal by activated carbon in O₂/CO₂ conditions

A study on simultaneous catalytic ozonation of Hg0 and NO using Mn–TiO2 catalyst at low flue gas temperatures

Experimental solubility and absorption mechanism of dilute SO2 in aqueous diethylene glycol dimethyl ether solution

Contact Info

Product

Resources

About

Catalytic oxidation and capture of elemental mercury from simulated flue gas using Mn-doped titanium dioxide

Cited by 8 publications

References 35 publications

Synergistic effect between H2O and SO2 on mercury removal by activated carbon in O2/CO2 conditions

Synergistic effect between H2O and SO2 on mercury removal by activated carbon in O2/CO2 conditions

A study on simultaneous catalytic ozonation of Hg0 and NO using Mn–TiO2 catalyst at low flue gas temperatures

Experimental solubility and absorption mechanism of dilute SO2 in aqueous diethylene glycol dimethyl ether solution

Contact Info

Product

Resources

About

Synergistic effect between H₂O and SO₂ on mercury removal by activated carbon in O₂/CO₂ conditions

Synergistic effect between H₂O and SO₂ on mercury removal by activated carbon in O₂/CO₂ conditions