Catalytic polymerization of the methyl ether of dimethylvinylethynylcarbinol

Kryazhev, Yu. G.; Cherkashin, Μ. I.; Yushmanova, T. I.; Kalikhman, I. D.; Baiborodina, Ye.N.; Shoshtakovskii, M.F.

doi:10.1016/0032-3950(69)90302-5

Cited by 4 publications

(2 citation statements)

References 3 publications

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“…Conjugated enynes, consisting of higher unsaturated systems, are also attractive candidates to provide polymers containing unsaturated bonds. Although several attempts to polymerize enyne derivatives have been reported, they are generally not informative enough in terms of the polymerization behavior and the polymer structure . Recently, several controlled polymerizations of enyne derivatives have been gradually developed, including the anionic polymerization of lithium acetylides of 1-buten-3-yne and 2-methyl-1-buten-3-yne, which gives polymers having terminal acetylene moieties in the side chain.…”

Section: Introductionmentioning

confidence: 99%

Investigation on Radical Polymerization Behavior of 4-Substituted Aromatic Enynes. Experimental, ESR, and Computational Studies

2001

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The radical polymerization of 4-substituted aromatic enynes was carried out to obtain polymers containing acetylene moieties in the side chain. The polymers prepared at 60 °C consisted of 1,2-polymerized units (i.e., units having pendent acetylene moieties) regardless of the character of the substituents. The Q and e values of enyne monomers were estimated from copolymerization with methyl methacrylate. The large Q values (Q ) 4.1-5.5) indicate that the propagating radicals are highly stabilized by the arylethynyl groups which is supported by both the ESR experiments and molecular orbital calculations. The e values (e ) -0.1 to -0.6) were in good agreement with the Hammett σ p values of the substituents on the benzene rings.

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Section: Introductionmentioning

confidence: 99%

Investigation on Radical Polymerization Behavior of 4-Substituted Aromatic Enynes. Experimental, ESR, and Computational Studies

2001

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“…Conjugated enynes are also attractive candidates to provide unsaturated polymers containing acetylene, diene, and allene moieties by 1,2-, 3,4-, and 1,4-polymerizations, respectively. Although the radical, cationic, and anionic polymerizations of some 4-substituted or 2,4-disubstituted enynes have been reported to proceed through 1,2-polymerization, most of which gave an insufficient information on the polymer structure and the polymerization behavior. Namely, polymers having well-defined structures and molecular weights have not been obtained yet from any conjugated enynes .…”

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confidence: 99%