Catalytic process for decolorizing yellow plume

Abstract

Yellow-colored exhaust gas streams from internal engines or gas turbines, frequently referred to as "yellow plume," contain nitrogen dioxide (NO 2 ) at concentrations as low as 15 ppm. The process developed in this work for decolorizing the yellow plume is based on reduction of NO 2 to NO utilizing a combination of a Pt catalyst and a reducing agent. A stoichiometric excess of carbon monoxide, diesel oil, methanol or ethanol were used as reducing agents. Depending on the type of the reductant, the active temperature window of NO 2 reduction was varied with methanol and CO being active at lower temperatures and ethanol and diesel oil at higher temperatures. By changing the Pt loading of the catalysts the active temperature window of NO 2 reduction was also changed, higher loading Pt catalysts being active at lower temperatures. This scheme of NO 2 reduction process was verified in a pilot-scale test with the real exhaust gas from the gas turbine power plant, showing 96% of NO 2 reduction at the stack temperatures of 102-123 o C and at space velocities of 28,000-95,000 h −1 with inherent CO in the exhaust gas as the reducing agent.

Mechanism Research and Countermeasure Analysis of Yellow Plume during the Gas Turbine Start-Up Period

“…Simultaneously, the flue gas temperature should rise to improve the efficiency of the HRSG. (2) Catalytic reduction method [21] should be adopted in the flue. The NO 2 would be reduced to NO, thus yellow plume would be eliminated.…”