Catalytic properties of chloro-tris[tri(2-thienyl)phosphine]-rhodium(I) in hydrogenation of unsaturated compounds

Gol'dfarb, Ya. L.; Клабуновский, Е. И.; Dudinov, A. A.; Sukhobok, L. N.; Павлов, В. А.; Polkovnikov, B. D.; Литвинов, В. П.

doi:10.1007/bf00954298

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Rhodium-catalyzed Isomerizations2

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“…Gol'dfarb et al reported their work on allyl arene isomerization during the hydrogenation of allylbenzene with chloro-tris(tri(phenylphosphine)-rhodium(I) (Wilkinson's complex) or chloro-tris[tri-(2-thienyl)phosphine]-rhodium(I) complexes. 570 Under standard hydrogenation conditions, the total amount of cis-and trans-isomers did not exceed 3%. However, when hydrogenation was conducted on allylbenzene that had been treated with sodium borohydride, a significant amount of isomerized material was observed after 30 min (∼20% trans and <3% cis).…”

Section: Rhodium-catalyzed Isomerizationsmentioning

confidence: 92%

“…Gol’dfarb et al reported their work on allyl arene isomerization during the hydrogenation of allylbenzene with chloro-tris(tri(phenylphosphine)-rhodium(I) (Wilkinson’s complex) or chloro-tris[tri-(2-thienyl)phosphine]-rhodium(I) complexes . Under standard hydrogenation conditions, the total amount of cis - and trans -isomers did not exceed 3%.…”

Section: Transition Metal-mediated Isomerizations Of Allylbenzenesmentioning

confidence: 99%

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