2001
DOI: 10.1016/s0167-7322(01)00148-9
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Cationic effect in agueous solutions of 1:1 electrolytes by Raman spectral data

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Cited by 13 publications
(7 citation statements)
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“…However, the values of DNHBW of saline solutions (AuNT and sAuNT) are still significantly higher than that of DI water-based saline solution. As shown in the literature, almost tetrahedral structure of liquid water with two O–H bonds can be disrupted by the dissolving process of NaCl [ 84 , 85 ]. Different treatments on water confirm the LSPR effects with respect to the corresponding AuNT water owning different values of DNHBW [ 67 ].…”
Section: Resultsmentioning
confidence: 99%
“…However, the values of DNHBW of saline solutions (AuNT and sAuNT) are still significantly higher than that of DI water-based saline solution. As shown in the literature, almost tetrahedral structure of liquid water with two O–H bonds can be disrupted by the dissolving process of NaCl [ 84 , 85 ]. Different treatments on water confirm the LSPR effects with respect to the corresponding AuNT water owning different values of DNHBW [ 67 ].…”
Section: Resultsmentioning
confidence: 99%
“…Nevertheless, the DNHBW of saline solution (AuNT and sAuNT) is still markedly higher than that of saline solution (DI). Water's almost tetrahedral structure, with two O-H bonds, is disrupted by the dissolution of NaCl 31 32 . Different water treatments confirm the LSPR effects with respect to the corresponding AuNT water having different DNHBWs, as shown in Table S1 and in the Supplementary Discussion (SD) .…”
Section: Resultsmentioning
confidence: 99%
“…There are many reports on the studying of the effect of dissolved electrolytes on the O-H stretching bands of water. [3][4][5][6][7][8][9][10][11][12][13][14][15][16][17] Anions, which interact directly with the hydrogen atoms of water molecules, were observed having heavier effect on the spectroscopic characteristics of the O-H stretching bands compared with cations which interact with the oxygen atoms of water molecules. Two types of anions, so called '' structure breaking '' and '' structure making '' anions, have been roughly classified in terms of the properties of the interactions between anions and water molecules.…”
Section: Introductionmentioning
confidence: 98%