Cationic Interfacial Layer toward a LiF-Enriched Interphase for Stable Li Metal Batteries

Ju, Zhijin; Jin, Chengbin; Cai, Xiaohan; Sheng, Ouwei; Wang, Juncheng; Luo, Jianmin; Yuan, Huadong; Lu, Gongxun; Liang, Zheng

doi:10.1021/acsenergylett.2c02379

Cited by 46 publications

(17 citation statements)

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“…Improving the ionic conductivity of solid electrolytes and composite cathodes is an effective way to make batteries stably operate at room temperature, low pressure, and high current density. Furthermore, advanced characterization techniques such as cryo-electron microscopy are effective in deeply understanding lithium dendrite growth and unstable interfacial issues to further promote the development of ASSLBs. − …”

Section: Enhancement Strategies For Asslbsmentioning

confidence: 99%

Current Status and Enhancement Strategies for All-Solid-State Lithium Batteries

et al. 2023

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Conspectus All-solid-state lithium batteries have received considerable attention in recent years with the ever-growing demand for efficient and safe energy storage technologies. However, key issues remain unsolved and hinder full-scale commercialization of all-solid-state lithium batteries. Previously, most discussion only focused on how to achieve high energy density from the theoretical perspective. Herein, we analyze the real cases of different kinds of all-solid-state lithium batteries with high energy density to understand the current status, including all-solid-state lithium-ion batteries, all-solid-state lithium metal batteries, and all-solid-state lithium–sulfur batteries. First, we propose a general calculation method to visually compare the above battery systems partly due to no normative parameters for solid-state batteries. After then, we discuss and interpret the key parameters and current situation of all-solid-state lithium batteries. Through the summary and analysis of the frontier, one can find that, although some breakthrough has been made in energy density and areal capacity for solid-state batteries, there are still many aspects to be improved such as power density and rate performance. Therefore, in response to the challenges, we propose possible directions for future development, including the ways to prepare different kinds of solid electrolyte films to reduce the proportion of inactive substances in the cell. The advantages and disadvantages are discussed about three typical solid-state electrolyte films (inorganic solid electrolyte, solid polymer electrolyte, and composite solid electrolyte). In addition, potential candidate anodes with high capacity and cathodes with high voltage and/or high capacity are also discussed in details. The combination of lithium metal anodes with ultrahigh capacity and cathodes with both high capacity and high voltage is the current mainstream direction. However, the interface problems have become the most pressing factor on the application. Therefore, we introduce the origin of interfaces and interphases and discuss how to build a stable electrode/solid electrolyte interface. One thing is clear that artificial solid electrolyte interphases and composite solid electrolytes are effective to obtain stable anode/solid electrolyte interfaces, which can prevent lithium from constantly reacting with solid electrolytes, ensure the uniform lithium deposition and prevent the formation of lithium dendrites. For the cathode/solid electrolyte interface, reasonable composite cathodes, multilayer design, and composite solid electrolytes can optimize the electrode and interface for stable cycles at high voltages and high current densities. Furthermore, the contribution of high-throughput computations and machine learning is introduced in accelerating materials screening and development. Among them, progress has been made in solid electrolytes and artificial solid electrolyte interphases through materials genome engineering and machine learning. Finally, we provide some out...

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Section: Enhancement Strategies For Asslbsmentioning

confidence: 99%

Current Status and Enhancement Strategies for All-Solid-State Lithium Batteries

et al. 2023

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“…Unfortunately, dendrites were formed on the anode surface indicating the inefficiency of MCT in regulating the Li nucleation. However, the corresponding EDS analysis (Figure S20) shows that there are relatively few sulfur atoms on the surface of cycled Li metal anode, reflecting the strong shielding of MCT to LiPSs diffusion. ,, Such excellent performance shows strong competitiveness of MCT interlayer in the strategies based on the LiPSs barrier interlayer engineering (Table S1), offering a potential solution for high-energy LSBs.…”

Section: Resultsmentioning

confidence: 99%

Multifunctional α-MoO₃ Nanobelt Interlayer with the Capacity Compensation Effect for High-Energy Lithium–Sulfur Batteries

Yue

Zhang

Chen

et al. 2023

ACS Appl. Mater. Interfaces

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Spatial hindrance of lithium polysulfide (LiPS) diffusion by inserting a barrier interlayer has been deemed as an effective strategy to restrict the shuttle effect in lithium−sulfur batteries (LSBs). However, the extra interlayer without reversible capacity production inevitably reduces the actual energy density of the battery. Herein, a freestanding α-MoO 3 nanobelt interlayer with the decoration of TiN nanoparticles and carbon nanotubes (denoted as MCT) is established. To investigate the capacity compensation effect of the MCT during cell operations, X-ray absorption near-edge spectrometry is conducted. It is revealed that MoO 3 can sustain a reversible Li intercalation/deintercalation in a voltage range of 1.8−2.8 V, providing 180 mAh g −1 of extra capacity for compensating sulfur cathode. In addition, the adsorption of the lithiated α-MoO 3 toward LiPSs is further evaluated. By matching a high-loading sulfur cathode (3.0 mg cm −2 ), a superior capacity of 713.3 mAh g −1 can be retained after 100 cycles under the MCT assistance.

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“…In order to evaluate the advantages of batteries, various performance indicators, which include the production cost, energy storage capacity density, rate performance, lifetime, and cyclic stability, are used [ 4 , 5 , 6 ]. The electrochemical properties of Li-ion batteries depend on the electrode materials which play a major role as a key component [ 7 , 8 , 9 , 10 , 11 ]. Thus, developing a suitable and high-performance electrode material is of special significance.…”

Section: Introductionmentioning

confidence: 99%

Fabrication of a Biomass-Derived Activated Carbon-Based Anode for High-Performance Li-Ion Batteries

et al. 2023

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Porous carbons are highly attractive and demanding materials which could be prepared using biomass waste; thus, they are promising for enhanced electrochemical capacitive performance in capacitors and cycling efficiency in Li-ion batteries. Herein, biomass (rice husk)-derived activated carbon was synthesized via a facile chemical route and used as anode materials for Li-ion batteries. Various characterization techniques were used to study the structural and morphological properties of the prepared activated carbon. The prepared activated carbon possessed a carbon structure with a certain degree of amorphousness. The morphology of the activated carbon was of spherical shape with a particle size of ~40–90 nm. Raman studies revealed the characteristic peaks of carbon present in the prepared activated carbon. The electrochemical studies evaluated for the fabricated coin cell with the activated carbon anode showed that the cell delivered a discharge capacity of ~321 mAhg−1 at a current density of 100 mAg−1 for the first cycle, and maintained a capacity of ~253 mAhg−1 for 400 cycles. The capacity retention was found to be higher (~81%) with 92.3% coulombic efficiency even after 400 cycles, which showed excellent cyclic reversibility and stability compared to commercial activated carbon. These results allow the waste biomass-derived anode to overcome the problem of cyclic stability and capacity performance. This study provides an insight for the fabrication of anodes from the rice husk which can be redirected into creating valuable renewable energy storage devices in the future, and the product could be a socially and ethically acceptable product.

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Cationic Interfacial Layer toward a LiF-Enriched Interphase for Stable Li Metal Batteries

Cited by 46 publications

References 47 publications

Current Status and Enhancement Strategies for All-Solid-State Lithium Batteries

Current Status and Enhancement Strategies for All-Solid-State Lithium Batteries

Multifunctional α-MoO₃ Nanobelt Interlayer with the Capacity Compensation Effect for High-Energy Lithium–Sulfur Batteries

Fabrication of a Biomass-Derived Activated Carbon-Based Anode for High-Performance Li-Ion Batteries

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Cationic Interfacial Layer toward a LiF-Enriched Interphase for Stable Li Metal Batteries

Cited by 46 publications

References 47 publications

Current Status and Enhancement Strategies for All-Solid-State Lithium Batteries

Current Status and Enhancement Strategies for All-Solid-State Lithium Batteries

Multifunctional α-MoO3 Nanobelt Interlayer with the Capacity Compensation Effect for High-Energy Lithium–Sulfur Batteries

Fabrication of a Biomass-Derived Activated Carbon-Based Anode for High-Performance Li-Ion Batteries

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Product

Resources

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Multifunctional α-MoO₃ Nanobelt Interlayer with the Capacity Compensation Effect for High-Energy Lithium–Sulfur Batteries