Cationic Polymerization of Vinyl Monomers Under the Action of Metalorganic Compounds

Lyapkov, A. A.; Ionova, E. I.; Bondaletov, V. G.; Pestryakov, Alexey

doi:10.5772/48180

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2014

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“…The process of DCPD cation polymerization proceeds under the influence of a catalyst system AlEt 2 Cl : TiCl 4 and in the presence only of TiCl 4 [10,11]. This is evidenced by the close value k P equal to 2.14 ± 0.04 l/(mol ⋅ s).…”

Section: --mentioning

confidence: 97%

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Modeling of the Kinetic Experiment of Dicyclopentadiene Olygomerization

Lyapkov¹,

Bondaletov²,

Melnik

et al. 2014

AMR

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Regularities of the dicyclopentadiene cationic oligomerization under influence of the catalytic system AlEt2Cl: TiCl4 in toluene solution were studied. The most probable mechanism of polymerization in this system is the propagation chain on the contact or solvate-separated ion pairs. The effective rate constant of solvation of the catalyst and chain propagation were calculated. The thermal oligomerization effect and heat of the catalyst system components solvation are determined by heat of oligomerization raw material containing dicyclopentadiene. When taking into account the data of both material and thermal balance the experimental data were described adequately.

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Section: --mentioning

confidence: 97%

“…The study of dicyclopentadiene polymerization process by the influence of catalytic system AlEt 2 Cl: TiCl 4 started from receiving kinetics information in the adiabatic mixing reactor [10,11]. The methodology of the experiment and the structure of experimental setup adiabatic thermometry are described in detail in [12].…”

Section: Experimental Partmentioning

confidence: 99%