We investigate the upper mantle velocity structure through processing first arrival data from peaceful nuclear explosions. The reported 2D model has been obtained by ray tracing for a spherical Earth, unlike the classical plane-approximation approach with subsequent spherical symmetry corrections, which is not always applicable to a laterally heterogeneous subsurface. The upper mantle velocity highs and lows imaged to 200–220 km depths show obvious correlation with major structures of the craton basement. Namely, low-velocity zones are observed beneath basins, the largest (to 8.0–8.1 km/s) under the Vendian–Early Cambrian Sayan–Yenisei syneclise. A discontinuous high-velocity layer (8.6–8.7 km/s) at depths between 150 and 240 km is underlain by a zone of lower velocity (8.50–8.55 km/s) down to the 410 km discontinuity, where the velocity at the top of the transition zone is 9.4–9.5 km/s.

No abstract

A breakthrough "superoxide colloidal solution route" for low-temperature synthesis of barium and strontium stannate perovskites and their doped analogues was recently introduced. The synthesis starts from hydrogen peroxide-rich stannate solutions and yields a so-called "crystalline superoxide molecular cluster" that is converted by low temperature (<300 °C) to the respective perovskites. In this paper, the so-called "crystalline superoxide molecular cluster" is identified as a superoxide-free, barium trihydroxo-(hydroperoxo)peroxostannate, BaSn(OH) 3 (OOH)(OO) phase (BHHPS). EPR and Raman spectroscopy studies reveal the absence of superoxide in this crystalline phase. FTIR of the deuterated sample, 119 Sn NMR, and elemental analysis uncovered the empirical formula, H 4 O 7 SnBa with two peroxides per each tin element. Rietveld refinement of the XRD confirms the BHHPS cubic phase with replacement of the perovskite oxygen atoms by the OH-and OOH-ligands and peroxobridging groups.

The upper-mantle structure was studied from first-arrival data along the Meteorite profile, run using underground nuclear explosions. Unlike the layered, slightly inhomogeneous models in the previous works, emphasis was laid on lateral inhomogeneity at the minimum possible number of abrupt seismic boundaries. We used forward ray tracing of the traveltimes of refracted and overcritical reflected waves. The model obtained is characterized by considerable velocity variations, from 7.7 km/s in the Baikal Rift Zone to 8.0-8.45 km/s beneath the Tunguska syneclise. A layer of increased velocity (up to 8.5-8.6 km/s), 30-80 km thick, is distinguished at the base of seismic lithosphere. The depth of the layer top varies from 120 km in the northern Siberian craton to 210 km in its southeastern framing. It has been shown that, with crustal density anomalies excluded, the reduced gravity field is consistent with the upper-mantle velocity model.