2013
DOI: 10.1021/nn3054544
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Cause and Prevention of Moisture-Induced Degradation of Resistance Random Access Memory Nanodevices

Abstract: Dielectric thin films in nanodevices may absorb moisture, leading to physical changes and property/performance degradation, such as altered data storage and readout in resistance random access memory. Here we demonstrate using a nanometallic memory that such degradation proceeds via nanoporosity, which facilitates water wetting in otherwise nonwetting dielectrics. Electric degradation only occurs when the device is in the charge-storage state, which provides a nanoscale dielectrophoretic force directing H2O to… Show more

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Cited by 31 publications
(24 citation statements)
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“…Removing the ZnO NR sample from the water revealed that the modifi ed substrate had not been wetted by the water, while it can be fatal to electrical circuits that the unmodifi ed sample was completely wet. [ 35 ] Well-aligned, high-density, pillar-like ZnO NRs were successfully grown during the preparation of the device, as shown in the FESEM images (Figure 2 c). The memristive switching device was characterized by patterning Au top electrodes onto the NR array prior to surface treatment.…”
Section: Doi: 101002/adma201303017mentioning
confidence: 87%
“…Removing the ZnO NR sample from the water revealed that the modifi ed substrate had not been wetted by the water, while it can be fatal to electrical circuits that the unmodifi ed sample was completely wet. [ 35 ] Well-aligned, high-density, pillar-like ZnO NRs were successfully grown during the preparation of the device, as shown in the FESEM images (Figure 2 c). The memristive switching device was characterized by patterning Au top electrodes onto the NR array prior to surface treatment.…”
Section: Doi: 101002/adma201303017mentioning
confidence: 87%
“…Figure 4h shows the switching with single-atomic change, where the set and reset is feasible with a minimum energy of ±650 meV. However, there are several other effects such as the quality of the metal/oxide interface, quality of the environment, [43][44][45][46][47] and the material deposition technique that can have an influence on the conductance levels in ECBJ devices. Here, we must mention that the conductance of the devices can be changed sharply to a half integer value (i.e., 0.5 G o ) as shown in Figure S5d, Supporting Information.…”
Section: Wwwadvelectronicmatdementioning
confidence: 99%
“…It has been demonstrated that in many cases moisture (water reduction) is able to provide this counter electrode reaction, thus playing a crucial role for device operation and reliability. [50][51][52] Protons and moisture have also been considered as essential parts of TiO 2 -based VCM [53] and NiO-based TCM devices. [54] Thus, the choice of solid electrolyte determines the ReRAM cell's stability and the reproducibility of the switching characteristics and the device performance in general.…”
Section: Impact Of the Solid Electrolyte Materialsmentioning
confidence: 99%