Abstract. We performed a careful differential abundance analysis of individual components of six main sequence binaries with separations of a few hundreds of AU. To reduce analysis concerns, we selected systems with almost equal mass components. We were able to derive differential abundances of several elements with errors down to 0.01 dex in the best cases. We found that in four systems the two components have the same chemical composition, within these very severe limits. However, clear differences were found for the two remaining systems (HD 219542 and HD 200466), in both cases the primaries being more Fe-rich than the secondaries, by 0.091 ± 0.009 and 0.053 ± 0.024 dex respectively. Similar differences were found for most of the elements considered in our analysis; however, we found no appreciable difference for volatile elements and a trend for increasing abundance differences with increasing condensation temperature for individual elements, a result similar to that found for some single stars with planets by Smith et al. (2001). Finally, we note that HD 219542A has a Li-abundance comparable to those of Li-rich stars in old open clusters, while no Li is detected in the slightly cooler HD 219542B. We suggest that the primaries of these two systems have accreted rocky planets or the inner dust-rich part of a protoplanetary disk, likely due to gravitational perturbation caused by the presence of the companion.