Due to the key role of Fe(III) species in living organisms, realtime detection of Fe 3 + ions is an important topic for the accurate diagnosis of many diseases, such as Alzheimer's, Huntington's, and Parkinson's diseases. Here, soft long-chain alkyl groups serving as the grippers are introduced into the rigid porous skeleton through a one-step Suzuki-coupling reaction. Through the ion-induced dipole interaction of longchain alkyl groups with Fe 3 + ions, the resulting PAF solid exhibits excellent enrichment effect for metal elements.Accordingly, an absorption competition quenching (ACQ) phenomenon is observed leading to the selectivity and sensitivity for monitoring Fe 3 + ions in the presence of various interfering ions. The sensing performance with the detection limit of 5.34 × 10 À 6 M far exceeds that of other porous solids including MOFs, ZIFs, COPs, and PNTs, etc. This work pioneers an efficient strategy that introducing long-chain alkanes as the grippers for the design of advanced sensors for practical application.