2005
DOI: 10.1007/s10853-005-3939-7
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Cd(S(1 − x) + CO3(x)) thin films by chemical synthesis

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Cited by 13 publications
(5 citation statements)
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“…and their slow recombination with S 2− ions which leads to the spontaneous formation of the MS precipitate in an easily controlled process. The growth of PbS is therefore carried out according to the following steps: (a) by mixing Pb(CH 3 CO 3 ) 2 , KOH, and NH 4 NO 3 , to produce the coordination complex, [Pb(NH 3 ) 4 ] 2 is generated indirectly; (b) The S 2− ions are found in the solution and generated by the thiourea decomposition in alkaline solution; (c) the aforementioned steps allow the slow process at the substrate surface to take place predominantly over direct hydrolysis of thiourea in the bulk of the reaction bath as follows [15]:…”
Section: Methodsmentioning
confidence: 99%
“…and their slow recombination with S 2− ions which leads to the spontaneous formation of the MS precipitate in an easily controlled process. The growth of PbS is therefore carried out according to the following steps: (a) by mixing Pb(CH 3 CO 3 ) 2 , KOH, and NH 4 NO 3 , to produce the coordination complex, [Pb(NH 3 ) 4 ] 2 is generated indirectly; (b) The S 2− ions are found in the solution and generated by the thiourea decomposition in alkaline solution; (c) the aforementioned steps allow the slow process at the substrate surface to take place predominantly over direct hydrolysis of thiourea in the bulk of the reaction bath as follows [15]:…”
Section: Methodsmentioning
confidence: 99%
“…1a shows a FE-SEM high magnification micrograph of this sample, it can be seen that the chemical compound consisted in a randomly agglomeration of rhombohedral microcrystalline structures. As this rhombohedral phase of CdCO 3 has the same aspect of the rhombohedral phase of calcite (CaCO 3 ), both microcrystalline materials show similar structures (they look cubic at first glance); 20,62 then, indicating a morphology typically exhibited by the cadmium carbonate chemical compound, as has been reported in the literature. 20,62 Micro-particles exhibiting flat surfaces and sharp/round edges and corners with a mean size of about 5.8 μm can be observed.…”
Section: Resultssupporting
confidence: 70%
“…As this rhombohedral phase of CdCO 3 has the same aspect of the rhombohedral phase of calcite (CaCO 3 ), both microcrystalline materials show similar structures (they look cubic at first glance); 20,62 then, indicating a morphology typically exhibited by the cadmium carbonate chemical compound, as has been reported in the literature. 20,62 Micro-particles exhibiting flat surfaces and sharp/round edges and corners with a mean size of about 5.8 μm can be observed. Those rhombohedral micro-particles are enclosed by {104} faces, 63–67 exhibiting roughened surfaces (a “sandblasted glass surface” aspect, i.e.…”
Section: Resultssupporting
confidence: 70%
“…11,12 More recently, a few papers describing deposition of composite films, emphasizing the composite nature of the films, have appeared in the literature. [13][14][15][16] However, *To whom correspondence should be addressed. E-mail: gary.hodes@ weizmann.ac.il.…”
Section: Introductionmentioning
confidence: 99%
“…More recently, a few papers describing deposition of composite films, emphasizing the composite nature of the films, have appeared in the literature. However, there is still little fundamental understanding and ability to predict the nature of a CBD composite film.…”
Section: Introductionmentioning
confidence: 99%