Cellulose Nanocrystals Induced Loose and Porous Graphite Phase Carbon Nitride/Porous Carbon Composites for Capturing and Determining of Organochlorine Pesticides from Water and Fruit Juice by Solid-Phase Microextraction

Abstract

Herein, novel, loose, and porous graphite phase carbon nitride/porous carbon (g-C3N4@PC) composites were prepared by decorating cellulose nanocrystals (CNCs). The characterization results demonstrate that the as-prepared composites presented high specific surface areas, porous structures, and abundant chemical groups, with the modification of CNCs. In view of the unique advantages, g-C3N4@PC was used as the coating material for the solid-phase microextraction (SPME) of organochlorine pesticides (OCPs) in water and juice samples. The g-C3N4@PC-coated fibers showed better extraction efficiencies than commercial fibers (100/7 μm PDMS and PA) toward the OCPs, with the enrichment factors of the g-C3N4@PC-coated fibers 5–30 times higher than the latter. Using a gas chromatography–mass spectrometry (GC-MS) instrument, the g-C3N4@PC-coated fibers exhibited a gratifying analytical performance for determining low concentrations of OCPs, with a wide linear range (0.1–1600 ng L−1 for water; 0.1–1000 ng L−1 for juice), low limits of detection (0.0141–0.0942 ng L−1 for water; 0.0245–0.0777 ng L−1 for juice), and good reproducibility and repeatability in optimal conditions. The established method showed good sensitivity and recovery in the determination of OCPs in the water and fruit juice samples, which displayed broad prospects for analyzing organic pollutants from environmental samples.

Physisorption Behaviors of Organochlorine Pesticides on the InP3 Monolayer from Theoretical Insight

“…To protect human health and restore the ecological environment, many analytical methods have been established to monitor residual OCP, such as gas chromatography–mass spectrometry (GC-MS), triple quadrupole mass analysis (GC-MS/MS), and so on. , Sample pretreatment is the fundamental step in the process of pesticide detection using these methods. Owing to high sensitivity, straightforward operation, and solvent-free mode, solid-phase microextraction (SPME) has been the widely used sample pretreatment technique, − wherein the coating material of SPME plays an important role in the sensitivity and selectivity during the detection of OCP. , …”