Cellulosic materials from pea (Pisum Sativum) and broad beans (Vicia Faba) pods agro-industrial residues

Kassab, Zineb; Abdellaoui, Youness; Salim, Mohamed Hamid; Achaby, Mounir El

doi:10.1016/j.matlet.2020.128539

Cited by 56 publications

(34 citation statements)

References 10 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Due to its renewability and biodegradability, the use of lignocellulosic-rich wastes can yield environmentally friendly materials through cost-effective processes with low environmental impact [4,5]. Several authors have reported the use of plant residues to obtain lignocellulosic fractions with potential application for biodiesel production [6], catalysts for biodiesel synthesis [7], antioxidant and antimicrobial materials [8,9] as well as reinforcing agents [10,11]. Particularly, cellulose and its derivatives extracted from biomass, such as cellulose microfibers (CMFs) and cellulose nanofibers, are highlighted renewable materials at the micro-and nanoscale, respectively, with low density, good compatibility, and excellent mechanical properties [12].…”

Section: Introductionmentioning

confidence: 99%

Valorization of Rice Straw into Cellulose Microfibers for the Reinforcement of Thermoplastic Corn Starch Films

et al. 2021

View full text Add to dashboard Cite

In the present study, agro-food waste derived rice straw (RS) was valorized into cellulose microfibers (CMFs) using a green process of combined ultrasound and heating treatments and were thereafter used to improve the physical properties of thermoplastic starch films (TPS). Mechanical defibrillation of the fibers gave rise to CMFs with cumulative frequencies of length and diameters below 200 and 5–15 µm, respectively. The resultant CMFs were successfully incorporated at, 1, 3, and 5 wt% into TPS by melt mixing and also starch was subjected to dry heating (DH) modification to yield TPS modified by dry heating (TPSDH). The resultant materials were finally shaped into films by thermo-compression and characterized. It was observed that both DH modification and fiber incorporation at 3 and 5 wt% loadings interfered with the starch gelatinization, leading to non-gelatinized starch granules in the biopolymer matrix. Thermo-compressed films prepared with both types of starches and reinforced with 3 wt% CMFs were more rigid (percentage increases of ~215% for TPS and ~207% for the TPSDH), more resistant to break (~100% for TPS and ~60% for TPSDH), but also less extensible (~53% for TPS and ~78% for TPSDH). The incorporation of CMFs into the TPS matrix at the highest contents also promoted a decrease in water vapor (~15%) and oxygen permeabilities (~30%). Finally, all the TPS composite films showed low changes in terms of optical properties and equilibrium moisture, being less soluble in water than the TPSDH films.

show abstract

Section: Introductionmentioning

confidence: 99%

Valorization of Rice Straw into Cellulose Microfibers for the Reinforcement of Thermoplastic Corn Starch Films

et al. 2021

View full text Add to dashboard Cite

show abstract

“…At Fig. 3, it is possible to observe some characteristic bands of plant materials: two bands related to the stretching vibrations of the -OH group in cellulose molecules that have intra and intermolecular hydrogen bonds in 3323 cm -1 (Wu et al, 2021); stretching vibrations of groups O -C and C -H in 2895 cm -1 In seeds, the 1603 cm -1 band referring to the asymmetric deformation of the CH3 groups is attributed to lignin and xylem (Kassab, Abdellaoui, Salim, & El Achaby, 2020). The bands at 1636 cm -1 and 1318 cm -1 for the cellulose sample are characteristic of vibrations of elongation of the glucose ring referring to cellulose (Cheng, Huang, Wang, & Zhang, 2016).…”

Section: Attenuated Total Reflectance With Fourier Transform Infrared Spectroscopy (Atr/ftir)mentioning

confidence: 99%

Sementes de açaí (Euterpe precatoria Mart.) como uma nova fonte alternativa de celulose: Extração e caracterização

Barros¹,

Oliveira²,

Pessoa³

et al. 2021

RSD

View full text Add to dashboard Cite

O açaí (Euterpe precatoria Mart.) é uma planta amplamente cultivada na região norte do Brasil. Seus frutos vêm ganhando destaque mundial devido aos inúmeros benefícios para a saúde humana. Consequentemente, a produção de celulose aumentou consideravelmente nos últimos anos, gerando uma quantidade significativa de resíduos (principalmente sementes). Como esses resíduos não têm uma destinação adequada, eles são descartados no meio ambiente ou incinerados, causando inúmeros impactos ambientais. Com o objetivo de apresentar alternativas de aplicação desses resíduos, este trabalho teve como objetivo avaliar o conteúdo lignocelulósico das sementes de açaí - extratos, cinzas, lignina, celulose (α-celulose e hemicelulose) - além de extrair e caracterizar a celulose obtida desse abundante resíduo. As sementes e a celulose extraída foram caracterizadas por diversas técnicas: fluorescência de raios X (XRF), difração de raios X (XRD), refletância total atenuada com espectroscopia de infravermelho por transformada de Fourier (ATR / FTIR) e termogravimetria (TGA). Neste estudo, foi confirmado o alto potencial do uso da semente de açaí como fonte alternativa de celulose, uma vez que apresenta 45,5% desse polímero e todas as técnicas de caracterização mostram a pureza da celulose extraída (tipo I).

show abstract

“…The role of the two treatments above is the removal of non-cellulosic components presented in the raw matter, namely lignin, hemicellulose, and other extractive substances, leading to the production of purified cellulose microfibers (CMF) [ 8 , 32 ]. CMF consists of a mixture of amorphous and crystalline regions and exhibits a fiber diameter generally of several micrometers [ 6 , 33 ].…”

Section: Introductionmentioning

confidence: 99%

“…The use of acid hydrolysis process to breakdown the purified cellulose fibers is the most widely applied technique, where the cellulose fibers are subjected to concentrated acid to remove the amorphous domains of the cellulose chains and leaving the crystalline domains unaltered, named cellulose nanocrystals (CNC) [ 1 , 6 , 9 ]. Hydrolysis conditions such as temperature, reaction time, the concentration used, and type of acid; need to be controlled during the acid hydrolysis process because the change of these factors directly affects CNC characteristics [ 6 ]. In the hydrolysis process, various forms of inorganic acids can be used, including sulfuric acid (H 2 SO 4 ) [ 9 ], phosphoric acid (H 3 PO 4 ) [ 1 ], a mixture of citric acid (C 6 H 8 O 7 ), and hydrochloric acid (HCl) [ 1 ].…”

Section: Introductionmentioning

confidence: 99%

“…In the hydrolysis process, various forms of inorganic acids can be used, including sulfuric acid (H 2 SO 4 ) [ 9 ], phosphoric acid (H 3 PO 4 ) [ 1 ], a mixture of citric acid (C 6 H 8 O 7 ), and hydrochloric acid (HCl) [ 1 ]. The hydrolysis by sulfuric acid attaches anionic sulfate groups to the cellulose surface, while phosphoric acid generates phosphate groups [ 1 , 6 ]. Hydrochloric acid hydrolysis produces hydroxyl groups on the surface, whereas hydrolysis using the mixture of hydrochloric acid and citric acid was reported to result in carboxylate functionalized CNC [ 1 ].…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Artemisia annua Stems a New Sustainable Source for Cellulosic Materials: Production and Characterization of Cellulose Microfibers and Nanocrystals

Risite

Salim

Oudinot

et al. 2022

Waste Biomass Valor

Self Cite

View full text Add to dashboard Cite

In this study, Artemisia annua stem waste was identified, for the first time, as a potential natural source to produce cellulose microfibers (CMF), as well as cellulose nanocrystals (CNC) with unique functionalities by using various organic acids. The CMF extraction was carried out using alkali and bleaching treatments, while the CNC were isolated under acid hydrolysis by using sulfuric acid (S-CNC), phosphoric acid (P-CNC), and hydrochloric acid / citric acid mixture (C-CNC). The CMF and CNC physicochemical, structural, morphological, dimensional, and thermal properties were characterized. CMF with a yield of 53%, diameter of 5 to 30 µm and crystallinity of 57% were successfully obtained. In contrast, CNC showed a rod-like shape with an aspect ratio of 53, 95, and 64 and a crystallinity index of 84, 79, and 72% for S-CNC, P-CNC, and C-CNC, respectively. Results suggested that the type of acid significantly influenced the structure, morphology, and thermal stability of CNCs. Based on these results, Artemisia annua stem waste is a great candidate source for cellulose derivatives with excellent characteristics. Graphical Abstract

show abstract

Cellulosic materials from pea (Pisum Sativum) and broad beans (Vicia Faba) pods agro-industrial residues

Cited by 56 publications

References 10 publications

Valorization of Rice Straw into Cellulose Microfibers for the Reinforcement of Thermoplastic Corn Starch Films

Valorization of Rice Straw into Cellulose Microfibers for the Reinforcement of Thermoplastic Corn Starch Films

Sementes de açaí (Euterpe precatoria Mart.) como uma nova fonte alternativa de celulose: Extração e caracterização

Artemisia annua Stems a New Sustainable Source for Cellulosic Materials: Production and Characterization of Cellulose Microfibers and Nanocrystals

Contact Info

Product

Resources

About