“…This could be explained by two main reasons: First, the new enhanced elements of susceptibility tensor in domain wall resulting from lattice distortion or internal local electrical field by poling process [8]; and second, arbitrary reciprocal vectors provided by the antiparallel domains across the domain wall [10], which could compensate for the phase mismatch in the nonlinear optical process. Besides Cherenkov SH generation, many other Cherenkov-type nonlinear processes have been found, including sum frequency generation [11,12], third and higher order harmonic generation [13,14], difference frequency generation [15], and so on. Since NCR is a noncollinear auto-phase-matched frequency conversion process and is quite sensitive to the ferroelectric domain wall, it has been utilized as an effective tool for nondestructive diagnostics, microscopy [16] and ultrashort pulse characterization [12].…”