Cerium-based metal–organic framework-conducting polymer nanocomposites for supercapacitors

Chang, Yan-Ling; Tsai, Meng-Dian; Shen, Cheng-Hui; Huang, Chi-Wei; Wang, Yi‐Ching; Kung, Chung Wei

doi:10.1016/j.mtsust.2023.100449

Cited by 13 publications

(4 citation statements)

References 69 publications

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“…This ultra-high cycling stability and remarkable reversibility of Ce(COOH) 3 were first discovered in this work. In fact, as summarized in Table 1, the cycling stability and capacitance retention rate of Ce(COOH) 3 are the highest among the reported Ce-organic compounds to the best of our knowledge [18,21,36,[38][39][40][41][42]. Moreover, the cycling stability and capacitance retention rate of Ce(COOH) 3 also have substantial advantages among the other most reported metal-organic compounds known for their long cycle life, such as Ni 3 (HITP) 2 (90% after 10,000 cycles at 2 A g −1 ) [16], Co-MOF (96% after 10,000 cycles at 5 mA cm −2 ) [43], Ni/Co-MOF (89.8% after 12,000 cycles at 10 A g −1 ) [44], Cu 3 (HHTP) 2 (79.9% after 5000 cycles at 5 A g −1 ) [45], V-MOF (92.1% after 10,000 cycles at 1 A g −1 ) [46], Cr-MOF (85% after 10,000 cycles at 0.5 A g −1 ) [47], Mn-MOF (81.18% after 10,000 cycles at 10 A g −1 ) [48], and Fe-MOF (74.4% after 10,000 cycles at 1 A g −1 ) [49].…”

Section: Resultsmentioning

confidence: 88%

Ultra-High Cycling Stability of 3D Flower-like Ce(COOH)3 for Supercapacitor Electrode via a Facile and Scalable Strategy

He,

Wang,

Yang

et al. 2023

Molecules

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An electrode material with high performance, long durability, and low cost for supercapacitors has long been desired in academia and industry. Among all the factors that affect the electrochemical performance and cycling stability of electrode materials, the morphology and intrinsic structure characteristics are the most important. In this study, a novel 3D flower-like Ce(COOH)3 electrode material was designed by taking advantage of the Ce3+ and -COOH groups and fabricated by a one-pot microwave-assisted method. The morphology and structure characteristics of the sample were examined by SEM, EDS, TEM, XRD, FT-IR, XPS, N2 adsorption/desorption techniques, and the electrochemical behaviors were investigated in a three-electrode configuration. The Ce(COOH)3 electrode presents an excellent specific capacitance of 140 F g−1 at 1 A g−1, higher than many other previously reported Ce-based electrodes. In addition, it delivers high rate capability that retains 60% of its initial capacitance when the current density is magnified 20 times. Dramatically, the Ce(COOH)3 electrode exhibits an ultra-high cycling stability with capacitance retention of 107.9% after 60,000 cycles, which is the highest durability among reported Ce–organic compound electrodes to the best of our knowledge. The excellent electrochemical performance is ascribed to its intrinsic crystal structure and unique morphology. This work indicates that the 3D flower-like Ce(COOH)3 has significant potential for supercapacitor applications and the facile and scalable synthesis strategy can be extended to produce other metal–organic composite electrodes.

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Section: Resultsmentioning

confidence: 88%

Ultra-High Cycling Stability of 3D Flower-like Ce(COOH)3 for Supercapacitor Electrode via a Facile and Scalable Strategy

He,

Wang,

Yang

et al. 2023

Molecules

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“…It can protect the environment from pollutants while still meeting the current high demand for electricity. These capacitors are widely employed in digital communication systems, energy storage devices, power and defense equipment, hybrid cars, and other applications 4,5 . Supercapacitors have increased capacitance (F g −1 , F cm −2 ) because their electrodes have a large surface area 6–11 .…”

Section: Introductionmentioning

confidence: 99%

“…These capacitors are widely employed in digital communication systems, energy storage devices, power and defense equipment, hybrid cars, and other applications. 4,5 Supercapacitors have increased capacitance (F g À1 , F cm À2 ) because their electrodes have a large surface area. [6][7][8][9][10][11] Conducting polymers, metal oxides, and metal sulfides are acting as the supercapacitor materials.…”

Section: Introductionmentioning

confidence: 99%

Studies on improved stability and electrochemical activity of metal oxides/sulfides‐based polymer nanocomposites for energy storage applications

Xavier

2024

Polymer Engineering & Sci

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Poly (3‐methylthiophene) (P3MT) was modified by nickel oxide (NiO) and nickel sulfide (NiS) nanoparticles to enhance its electrochemical performance. The surface influence, crystalline structure, and electrochemical performance of the P3MT/NiO/NiS material were characterized and compared with that of pristine P3MT. It is found that surface modification can improve the structural stability of P3MT without decreasing its available specific capacitance. The electrochemical properties of synthesized P3MT/NiO/NiS electrode were evaluated using cyclic voltammetry and alternating current impedance techniques in 3 M KOH electrolyte. Specific capacitances of 253, 764, 932, and 1434 F g−1 were obtained for P3MT, P3MT/NiO, P3MT/NiS, and P3MT/NiO/NiS, respectively at 5 A g−1. This improvement is attributed to the synergistic effect of Ni2+ ions in the P3MT/NiO/NiS electrode material. The P3MT/NiO/NiS electrode in KOH has average specific energy and specific power densities of 1032 Wh kg−1 and 6192 W/kg, respectively. Only 2% of the capacitance's initial value is lost after 10,000 cycles. The resulting P3MT/NiO/NiS nanocomposite had very stable and porous layered structures. This work demonstrates that P3MT/NiO/NiS nanomaterials exhibit good structural stability and electrochemical performance, and are good material for supercapacitor applications.Highlights The P3MT/NiO/NiS nanocomposite is fabricated and characterized as supercapacitor electrode. The incorporation of NiO/NiS in the poly (3‐methylthiophene) has improved the electrochemical performance. The P3MT/NiO/NiS electrodes retained 98% of their specific capacitance after 10,000 cycles. The P3MT/NiO/NiS nanocomposite electrode showed specific capacitance of 1434 F g−1 at 5 A g−1. The stability of the nanocomposite was enhanced without altering its morphology and chemical structure.

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“…Within this category, one can find notable examples like nanoporous materials, tendrils, and nanotubes [18]. In some instances, metals are enhanced through amalgamation with metal-organic framework (MOF) materials [19,20].…”

Section: Introductionmentioning

confidence: 99%

Highly Wrinkled Porous Polypyrrole for the Enhancement of the Performance of an Fe2S3-Fe2O3/poly-O-amino Benzenethiol Supercapacitor from a Basic Medium

Rabia,

Abdallah Alnuwaiser,

Hasan

et al. 2023

Inorganics

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In this study, O-amino benzenethiol (OABT) was oxidized in one pot using Fe(NO3)3 to produce a novel Fe2S3-Fe2O3/poly O-amino benzenethiol (POABT), which showed a highly uniform morphology. At the same time, from SEM analysis, highly wrinkled porous polypyrrole (Ppy) and porous ball-like POABT structures prepared from the K2S2O8 route were evidenced by SEM and TEM analyses. A nanocomposite pseudo-supercapacitor (SC) was fabricated using Fe2S3-Fe2O3/POABT, and its performance was tested with and without incorporating Ppy in the paste. The results indicate that Ppy significantly increased the specific capacitance (CS) values, indicating an enhancement in charge storage. At a current density of 0.2 A/g, the CS values were 44 F/g and 161 F/g for the paste without and with Ppy, respectively. Additionally, the E was calculated, and the incorporation of Ppy resulted in a significant increase in E, reaching 30 W.h.kg−1; this was significantly higher than the value of 8.18 W.h.kg−1 observed without Ppy materials. This effect is likely due to the improved charge transfer facilitated by the presence of Ppy, as evidenced by the Nyquist plot, where the Rct values were 1.1 Ω and 2.1 Ω with and without Ppy, respectively. Overall, the low cost and significant technical advantages of this capacitor make it a promising candidate for commercial applications.

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Cerium-based metal–organic framework-conducting polymer nanocomposites for supercapacitors

Cited by 13 publications

References 69 publications

Ultra-High Cycling Stability of 3D Flower-like Ce(COOH)3 for Supercapacitor Electrode via a Facile and Scalable Strategy

Ultra-High Cycling Stability of 3D Flower-like Ce(COOH)3 for Supercapacitor Electrode via a Facile and Scalable Strategy

Studies on improved stability and electrochemical activity of metal oxides/sulfides‐based polymer nanocomposites for energy storage applications

Highly Wrinkled Porous Polypyrrole for the Enhancement of the Performance of an Fe2S3-Fe2O3/poly-O-amino Benzenethiol Supercapacitor from a Basic Medium

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