“…We used two separate analytical protocols for sulfates/silicates and sulfides/sulfosalts, respectively. For alunite, barite and dickite, the collected analytes were 27 Al, 31 P, 44 Ca, 49 Ti, 53 Cr, 55 Mn, 57 Fe, 65 Cu, 66 Zn, 71 Ga, 72 Ge, 75 As, 77 Se, 85 Rb, 88 Sr, 98 Mo, 107 Ag, 115 In, 118 Sn, 121 Sb, 137 Ba, 139 La, 140 Ce, 197 Au, 208 Pb, 209 Bi, 232 Th and 238 U. The internal standard isotopes used for data reduction were 27 Al (alunite and dickite) and 137 Ba (barite), based on contents confirmed previously by WDS.…”