CH3NH3PbI3 Perovskite/Fullerene Planar‐Heterojunction Hybrid Solar Cells

Jeng, Jun Yuan; Chiang, Yi Fang; Lee, Mu Huan; Peng, Shin Rung; Guo, Tzung Fang; Chen, Peter; Wen, Ten Chin

doi:10.1002/adma.201301327

Cited by 1,441 publications

(1,143 citation statements)

References 22 publications

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“…A PCBM/C 60 double fullerene layer was inserted between the perovskite and cathode as an electron acceptor and collection layer 19,20 . The PCBM layer was spun onto the perovskite layer followed by low-temperature thermal annealing at 100°C for varied durations of 0 to 60 min and the C 60 layer was thermal evaporated.…”

Section: Resultsmentioning

confidence: 99%

Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells

et al. 2014

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The large photocurrent hysteresis observed in many organometal trihalide perovskite solar cells has become a major hindrance impairing the ultimate performance and stability of these devices, while its origin was unknown. Here we demonstrate the trap states on the surface and grain boundaries of the perovskite materials to be the origin of photocurrent hysteresis and that the fullerene layers deposited on perovskites can effectively passivate these charge trap states and eliminate the notorious photocurrent hysteresis. Fullerenes deposited on the top of the perovskites reduce the trap density by two orders of magnitude and double the power conversion efficiency of CH 3 NH 3 PbI 3 solar cells. The elucidation of the origin of photocurrent hysteresis and its elimination by trap passivation in perovskite solar cells provides important directions for future enhancements to device efficiency.

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Section: Resultsmentioning

confidence: 99%

Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells

et al. 2014

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“…They are ideal candidates as efficient ETLs because of their low‐temperature fabrication, suitable energy level alignment, and decent electron mobility 102, 120, 122. Unfortunately, they possess the low electron mobility and photochemical instability 123.…”

Section: Device Structurementioning

confidence: 99%

Recent Progress on the Long‐Term Stability of Perovskite Solar Cells

et al. 2018

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As rapid progress has been achieved in emerging thin film solar cell technology, organic–inorganic hybrid perovskite solar cells (PVSCs) have aroused many concerns with several desired properties for photovoltaic applications, including large absorption coefficients, excellent carrier mobility, long charge carrier diffusion lengths, low‐cost, and unbelievable progress. Power conversion efficiencies increased from 3.8% in 2009 up to the current world record of 22.1%. However, poor long‐term stability of PVSCs limits the future commercial application. Here, the degradation mechanisms for unstable perovskite materials and their corresponding solar cells are discussed. The strategies for enhancing the stability of perovskite materials and PVSCs are also summarized. This review is expected to provide helpful insights for further enhancing the stability of perovskite materials and PVSCs in this exciting field.

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“…[ 31 ] The cells were made by thermally depositing C 60 61 BM/Al and obtained a 5.2% PCE by using one-step deposition method and a 7.4% PCE by using a sequential deposition method. [ 32 ] The PCE was improved to 12% when using CH 3 NH 3 PbI 3 prepared by coevaporation of CH 3 NH 3 I and PbI 2 .…”

Section: Planar P-i-n Structurementioning

confidence: 99%

Advances in Perovskite Solar Cells

et al. 2016

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widely commercialized, but possiblities to increase their performance are limited, because nowadays the so-called balance of systems (BoS) cost of PV modules makes up most of the cost. [ 1 ] As much of the BoS scales with area, performance improvement seems the only way to decrease the cost of PV power further. Therefore, new PV cells are sought either to allow for higher effi ciencies than what is possible with Si PV without cost increase, or, as explained in section 3.4, to provide lowcost added effi ciency to Si PV. Emerging solar cells such as dye-sensitized, bulkheterojunction and quantum-dot solar cells can be fabricated via low-temperature solution processing, that holds promise for low-cost large scale application, but best power conversion effi ciencies (PCE) are half of, or less than that of the best commercial Si PV cells. [ 2 ] This is where perovskite solar cells enter, as for the fi rst time in PV history it is possible to produce high-effi ciency cells at low monetary and energy costs, with apparent ease of fabrication from earth-abundant, readily available raw materials. The PCE for perovskite solar cells has increased from 2.2% to 20.1% since 2006, showing an inviting vista of commercialization. [ 3,4 ] Perovskite solar cells are named after the crystal structure of the light absorbers, the structure of the mineral CaTiO 3 . Many compounds with ABX 3 stoichiometry take this structure, where A and B are 12-and 8-coordinates cations, respectively, and X is the anion. [ 4 ] Of the many ABX 3 only few are suitable to be efficient light absorbers for solar cells due to requirements such as appropriate bandgap for good light-harvesting ability, energy level/band alignment with contacting materials, long charge carrier lifetime, τ, and high mobility, µ. Perovskites generally have divalent anions, and the strong electrostatic bonding mostly makes their (high) bandgaps not suitable for solar PV. Mitzi et al. initiated using perovskites containing halides, ammonium cations and Sn 2+ in optoelectronic devices, which formed the basis for the development of perovskites for solar cells. [ 5 ] Here we will focus on such halide perovskites, together with one divalent (Pb 2+ ) and one monovalent (mostly CH 3 NH 3 + ) cation. The most effi cient halide perovskite solar absorbers consist of organic ammonium ions (CH 3 NH 3 + or NH = CHNH 3 + ), Pb 2+ and halide ions (I − , Br − ).[ 4 ] CH 3 NH 3 PbI 3 possesses broad and intense light absorption. It is an ambipolar semiconductor (can be n-or p-type), and its charge carriers can have long diffusion lengths and lifetimes, which allow excellent PCE for solar cells made with it. [3][4][5][6] Another advantage of perovskite absorbers is the low-temperature solution-processing ability, which helps

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CH₃NH₃PbI₃ Perovskite/Fullerene Planar‐Heterojunction Hybrid Solar Cells

Cited by 1,441 publications

References 22 publications

Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells

Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells

Recent Progress on the Long‐Term Stability of Perovskite Solar Cells

Advances in Perovskite Solar Cells

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