Among coal-producing countries, China has witnessed the highest frequency and severity of coal fires. During mining in the re-mining face and the lower part of the thick coal seam (or coal seam group), second or multiple oxidations of the residual coal can readily occur in mined-out areas, severely increasing the risk of coal fires. The study of multiple oxidations of coal aids in the early detection of spontaneous combustion of remaining coal in the mined-out areas. The characteristics of coal fires are demonstrated using fresh coal samples (first-oxidized coal) and oxidized coal samples (second-oxidized coal) from four different ranks of coals. Proximate and elemental analysis, Fourier transform spectroscopy, and thermogravimetry-differential scanning calorimetry were adopted to investigate the quality, microcharacteristics, characteristic temperatures, and apparent activation energy of second-oxidized coal. In addition, the effect of spontaneous combustion at heating rates of 5.0, 10.0, and 15.0°C min -1 was studied. Compared with the four samples of first-oxidized coal, those of second-oxidized coals cause fire easily under the same conditions.
List of symbolsA, A k Pre-exponential factor (s -1 ) A ad Ash content in air-dried basis (%) bHeating rate (°C min -1 ) C daf C content of air-dried basis (%) da/dt Conversion rate (s -1 ) E a , E k Apparent activation energy (kJ mol -1 ) f(a)Function of degree of conversion (dimensionless) H daf H content of air-dried basis (%) M ad Moisture in air-dried basis (%) N daf N content of air-dried basis (%) R Universal gas constant (8.314 J mol -1 K -1 ) r Correlation coefficient (dimensionless) O daf O content of air-dried basis (%) S daf S content of air-dried basis (%) T Thermokinetic temperature (K) T 1 First characteristic temperature, critical temperature (°C) T 2 Second characteristic temperature, active temperature (°C) T 3 Third characteristic temperature, pyrolysis temperature (°C) T 4 Fourth characteristic temperature, ignition temperature (°C) T 5 Fifth characteristic temperature, burned-out temperature (°C)