Based on the chaos theory and related algorithm, largest Lyapunov analysis of current of laser-twin-wire pulse MIG welding process are performed from the point of view of nonlinear time sequence. Largest Lyapunov exponent (LLE) of characteristic current under different laser power were calculated, meanwhile synchronous high-speed photography was adopted to observe arc shape and droplet transfer. The results indicate that arc shape and the force state of droplets changes as a result of interactions between laser plasma and arc plasma. Addition of low power laser intensifies the interplay of two arcs, which decreases the stability of welding process. When laser power reaches to a certain extent, a stable cathod spot and a conductive channel are obtained for arcs. Stable welding process and small welding spatter are acquired.