Characterisation of PEO–Al2O3 composite polymer electrolytes

Tambelli, C.C.; Bloise, Antonio Carlos; Rosario, Adriane V.; Pereira, Ernesto C.; Magon, Cláudio José; Donoso, José Pedro

doi:10.1016/s0013-4686(01)00900-8

Cited by 138 publications

(87 citation statements)

References 31 publications

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“…In the same year, Feuillade and Perche reported the plasticization on a polymer with an aprotic solution containing alkali metal salts. PEO is among the most popular polymer host has been widely investigated due to its interesting characteristics such as good dimensional stability, high capacity in salt complexation, high ionic conductivity in amorphous state, good corrosion resistance, acceptable commercial cost, mechanical flexibility and chemical stability [6,55,70,74]. Notwithstanding these advantages, PEO also possesses some disadvantages which limit its technological application.…”

Section: Poly(ethylene Oxide)mentioning

confidence: 99%

A review of polymer electrolytes: fundamental, approaches and applications

Ngai

Ramesh

Juan

2016

Ionics

584

369

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In this paper, we review different types of polymer electrolytes, recent approaches and technological applications of polymer electrolytes. The report first discusses the characteristics, advantages and applications for three types of polymer electrolytes: gel polymer electrolytes, solid polymer electrolytes and composite polymer electrolytes. Next, we discuss the features and performance of different polymer hosts based on some important and recently published literature. Recent progress of some approaches used in improving the performance of the polymer electrolytes is highlighted. The last part of the review includes the technological applications of some electrical energy storing/converting devices: electrochemical capacitors, batteries, fuel cells and dye-sensitized solar cells. It is also stressed that the technological advancement in the polymer electrolytes plays a pivotal role in the development of energy storing/converting systems.

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Section: Poly(ethylene Oxide)mentioning

confidence: 99%

A review of polymer electrolytes: fundamental, approaches and applications

Ngai

Ramesh

Juan

2016

Ionics

584

369

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“…to the alkaline salt (Li + ), creating coordination bonds [4], [5]. However, its low ionic conductivity at low room temperature causes the limitation of the device applications [6].…”

Section: Introductionmentioning

confidence: 99%

Effects of the Addition of LiCF3SO3 Salt on the Conductivity, Thermal and Mechanical Properties of PEO-LiCF3SO3 Solid Polymer Electrolyte

Klongkan¹,

Pumchusak²

2015

IJCEA

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Abstract-Solid polymer electrolyte for lithium ion batteries consisting of polyethylene oxide (PEO) and lithium trifluoromethanesulfonate (LiCF 3 SO 3 ) was prepared by a ball milling method followed by a hot pressing process. Various contents of Li salts (5, 10, 15 and 20 wt %) were studied. The samples were investigated for crystallinity and glass transition temperature by DSC and ionic conductivity was measured by the impedance. XRD patterns confirmed the degree of crystallinity of solid polymer electrolyte. The mechanical property was measured by tensile testing machine. It was found that the PEO composite that composed of 15 wt% of LiCF 3 SO 3 exhibited the highest conductivity at room temperature as 1.00 × 10 -6 Scm -1 , whereas the glass transition temperature (T g ), the melting temperature (T m ) and the degree of crystallinity decreased with the increasing of Li salt content.Index Terms-Lithium salt, polyethylene oxide, solid polymer electrolyte.

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“…Thus, nano-sized filler particles such as SiO 2 , TiO 2 , and Al 2 O 3 have been intergraded into the solid polymer electrolytes to enhance the ionic conductivity [3][4][5][6][7]. It is believed that the ionic conductivity enhancement is due to the Lewis acid-base type interactions of mobile ionic species with the O 2− /OH − groups on the surface of the filler grains.…”

Section: Introductionmentioning

confidence: 99%

The effects of ceramic fillers on the PMMA-based polymer electrolyte systems

Tan

Siew

Pang

et al. 2007

Ionics

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The effects of ceramics fillers on the polymethylmethacrylate (PMMA)-based solid polymer electrolytes have been studied using ac impedance spectroscopy and infrared spectroscopy. The polymer film samples were prepared using solution cast technique, tetrahydrofuran (THF) used as a solvent, and ethylene carbonate (EC) has been used as plasticizer. Lithium triflate salt (LiCF 3 SO 3 ) has been incorporated into the polymer electrolyte systems. Two types of ceramic fillers, i.e., SiO 2 and Al 2 O 3 , were then implemented into the polymer electrolyte systems. The solutions were stirred for several hours before it is poured into petri dishes for drying under ambient air. After the film has formed, it was transferred into desiccator for further drying before the test. From the observation done by impedance spectroscopy, the room temperature conductivity for the highest conducting film from the (PMMA-ECLiCF 3 SO 3 ) system is 1.36×10 −5 S cm −1 . On addition of the SiO 2 filler and Al 2 O 3 filler, the conductivity are expected to increase in the order of ∼10 −4 S cm −1 . Infrared spectroscopy indicates complexation between the polymer and the plasticizer, the polymer and the salts, the plasticizer and the salts, and the polymer and the fillers. The interactions have been observed in the C=O band, C-O-C band, and the O-CH 3 band.

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Characterisation of PEO–Al2O3 composite polymer electrolytes

Cited by 138 publications

References 31 publications

A review of polymer electrolytes: fundamental, approaches and applications

A review of polymer electrolytes: fundamental, approaches and applications

Effects of the Addition of LiCF3SO3 Salt on the Conductivity, Thermal and Mechanical Properties of PEO-LiCF3SO3 Solid Polymer Electrolyte

The effects of ceramic fillers on the PMMA-based polymer electrolyte systems

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