In this study, Al/p-Si and Al/Bi 4 Ti 3 O 12 /p-Si structures are fabricated and their interface states (N ss ), the values of series resistance (R s ), and AC electrical conductivity (σ ac ) are obtained each as a function of temperature using admittance spectroscopy method which includes capacitance-voltage (C-V ) and conductance-voltage (G-V ) measurements. In addition, the effect of interfacial Bi 4 Ti 3 O 12 (BTO) layer on the performance of the structure is investigated. The voltagedependent profiles of N ss and R s are obtained from the high-low frequency capacitance method and the Nicollian method, respectively. Experimental results show that N ss and R s , as strong functions of temperature and applied bias voltage, each exhibit a peak, whose position shifts towards the reverse bias region, in the depletion region. Such a peak behavior is attributed to the particular distribution of N ss and the reordering and restructuring of N ss under the effect of temperature. The values of activation energy (E a ), obtained from the slope of the Arrhenius plot, of both structures are obtained to be bias voltage-independent, and the E a of the metal-ferroelectric-semiconductor (MFS) structure is found to be half that of the metal-semiconductor (MS) structure. Furthermore, other main electrical parameters, such as carrier concentration of acceptor atoms (N A ), built-in potential (V bi ), Fermi energy (E F ), image force barrier lowering (∆Φ b ), and barrier height (Φ b ), are extracted using reverse bias C −2 -V characteristics as a function of temperature.