Kepler-454 (KOI-273) is a relatively bright (V = 11.69 mag), Sun-like star that hosts a transiting planet candidate in a 10.6 day orbit. From spectroscopy, we estimate the stellar temperature to be 5687±50 K, its metallicity to be [m/H] = 0.32±0.08, and the projected rotational velocity to be v sin i<2.4 km s −1 . We combine these values with a study of the asteroseismic frequencies from short cadence Kepler data to estimate the stellar mass to be M 1.028 0.03 0.04 -+ , the radius to be 1.066±0.012 R e , and the age to be 5.25 1.39Gyr. We estimate the radius of the 10.6 day planet as 2.37±0.13 R ⊕ . Using 63 radial velocity observations obtained with the HARPS-N spectrograph on the Telescopio Nazionale Galileo and 36 observations made with the HIRES spectrograph at the Keck Observatory, we measure the mass of this planet to be 6.8±1.4 M ⊕ . We also detect two additional nontransiting companions, a planet with a minimum mass of 4.46±0.12 M J in a nearly circular 524 day orbit and a massive companion with a period >10 years and mass >12.1 M J . The 12 exoplanets with radii <2.7 R ⊕ and precise mass measurements appear to fall into two populations, with those <1.6 R ⊕ following an Earth-like composition curve and larger planets requiring a significant fraction of volatiles. With a density of 2.76±0.73 g cm −3 , Kepler-454b lies near the mass transition between these two populations and requires the presence of volatiles and/or H/He gas.