2007
DOI: 10.1021/ie0704750
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Characteristics of Wood Cellulose Fibers Treated with Periodate and Bisulfite

Abstract: Wood cellulose fibers were oxidized by periodate to obtain dialdehyde cellulose (DAC) fibers. The aldehyde group content, degrees of crystallinity and polymerization, and fiber length of treated fibers were characterized. The tensile strength of the test sheets made of treated fibers was also measured. The results show that periodate oxidation significantly increased the aldehyde group content and the dry and rewet tensile strengths of the test sheets. Sulfonation of the oxidized fibers by bisulfite improved t… Show more

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Cited by 54 publications
(29 citation statements)
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“…The dry strength then passed a maximum with increasing degree of oxidation. Both the dry and the wet strength of the sheets could be further increased by reacting the formed dialdehyde cellulose with bisulfite prior to sheet forming (Hou et al 2007). It was suggested that the increase in tensile strength of the sheets in this case was due to changes in the fibre surface morphology.…”
Section: Introductionmentioning
confidence: 89%
See 1 more Smart Citation
“…The dry strength then passed a maximum with increasing degree of oxidation. Both the dry and the wet strength of the sheets could be further increased by reacting the formed dialdehyde cellulose with bisulfite prior to sheet forming (Hou et al 2007). It was suggested that the increase in tensile strength of the sheets in this case was due to changes in the fibre surface morphology.…”
Section: Introductionmentioning
confidence: 89%
“…They found that both the dry and wet tensile strength increased with increasing degree of oxidation to a maximum and then decreased on further oxidation. Periodate oxidation has also recently been applied by Hou et al (2007), who also found that both dry and wet strength could be increased by periodate oxidation, but under their reaction conditions the strength was first decreased at low degrees of oxidation and then increased. The dry strength then passed a maximum with increasing degree of oxidation.…”
Section: Introductionmentioning
confidence: 99%
“…The acid groups remain dissociated throughout the pH range where such fibers are likely to be used. Hou et al (2008) also showed that sulfonation improved absorbency.…”
Section: Sulfonationmentioning
confidence: 94%
“…The absorptions at 1638 and 1639 cm 21 of CF and DAC, respectively, were the water absorption by the samples. 23 The free aldehyde group stretching vibrations at 1732 cm 21 and the semiacetal vibrations at 872 cm 21 in DAC proved the successful selective oxidation reaction of CF. The peaks at 1377 and 1395 cm 21 were the plane rocking vibrations of ACH 2 A.…”
Section: Article Wileyonlinelibrarycom/appmentioning
confidence: 95%