Characterization and Interpretation of the Aluminum Zone Refining through Infrared Thermographic Analysis

Abstract

High purity metals are nowadays increasingly in demand to serve in electronic, photovoltaic, and target materials industries. The zone refining process is the most common way to achieve high purity in the final step of metal purification. Zone length and crystal growth rate are the main parameters that control the zone refining process. To determine these values, information about temperature profiles in the molten zone is necessary due to its direct correlation with these values. As the determination of this profile is not practically achievable in the present, the novel approach of applying an infrared (IR) camera during the zone refining of 2N8 aluminum is the focus of the investigation in this work. The whole temperature profile of the region near the molten zone was recorded by IR camera during the entire running process. The zone length and the crystal growth rate at each thermographic image shooting moment were successfully extracted by thermographic analysis. Results showed that both factors varied significantly, which is in contrast to the assumption in literature about their stability while running under constant input power and heater movement velocity, though noticeable purification took place in all of these experiments. However, the impurity concentration during refinement fluctuated remarkably. This was well-demonstrated by the tendency of variation in crystal growth rate attained in this work. These results provide a better understanding of the mechanisms of zone refining with an inductive heater and contributes to the optimization of the process.

The Influence of Initial Purity Level on the Refining Efficiency of Aluminum via Zone Refining

“…Moreover, the zone length frequently varied even under the stable heater power and a constant heater movement velocity due to the high thermal conductive charge and crucible, leading the frequent failure of heat balance at the solid/liquid interface [6]. Therefore, a frequent adjustment of the power had to be carried out manually, according to the real zone length detected by an Infrared camera [16,22]. This allowed for a comparatively stable zone length as the heater moved.…”

A Liquid Metal Temperature Detection System Based on Multi-Node Sapphire Fiber Sensor

“…There are a large number of aluminum products in the manufacturing industry [2][3][4][5][6][7][8], and efficient production process control can reduce production costs and improve product quality. In the process of manufacturing casting products, the temperature control of molten aluminum is a key factor [3,[8][9][10][11]. In this sense, it is of great significance to control the temperature of molten aluminum to improve the performance of castings.…”

“…The practical infrared temperature measurement method and the k-type armored thermocouple measurement method are currently the two most commonly used ways to detect the temperature of molten metal [9,12,13]. Heeley et al [12] developed a new infrared thermometer based on an Indium Arsenide Antimony (InAsSb) photodiode, a trans-impedance amplifier, and a sapphire fiber optic cable.…”