Characterization of Gamma Irradiated Plasticized Carboxymethyl Cellulose (CMC)/Gum Arabic (GA) Polymer Blends as Absorbents for Dyestuffs

Ibrahim, Sayeda M.; Mousaa, I.M.; Ibrahim, Mervat S.

doi:10.1007/s12034-014-0666-1

Cited by 8 publications

(8 citation statements)

References 10 publications

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“…The authors attributed this rapid adsorption rate to external surface adsorption, assuming that all the adsorption sites are present on the exterior of the adsorbent . In another study, a polymer blend of carboxymethyl cellulose (CMC) and gum arabic was used for the adsorption of basic as well as acidic dyes …”

Section: Structure and Properties Of Gum Polysaccharidesmentioning

confidence: 99%

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Recent Progress on the Design and Applications of Polysaccharide‐Based Graft Copolymer Hydrogels as Adsorbents for Wastewater Purification

Mittal

Ray

Okamoto

2016

Macro Materials & Eng

131

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Gum polysaccharides are one of the most abundant bio‐based polymers. They are generally derived from plants as exudates or from microorganisms and have diverse applications in many industries, especially in the food industries where they are used as emulsifiers and thickeners. In their natural form, gum polysaccharides have poor mechanical and physical properties; therefore, they are frequently modified with various synthetic monomers such as acrylamide and acrylic acid using graft copolymerization. Graft copolymerization is one of the most trusted and widely used synthetic methods for the modification of gum polysaccharides. Gum polysaccharides modified in this way have improved mechanical and physicochemical properties. Furthermore, gum polysaccharides contain a variety of functional groups, for example, carboxylic acid and hydroxyl groups; therefore, they have been used extensively as adsorbents for the removal of different impurities from wastewater such as toxic heavy metal cations and synthetic dyes. Here, the chemical and physical properties of gum polysaccharides, different methods of graft copolymerization, and the use of graft copolymer gum‐polysaccharide‐based hydrogels are reviewed in detail for the removal of toxic heavy metal cations and synthetic dyes from aqueous solutions.

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Section: Structure and Properties Of Gum Polysaccharidesmentioning

confidence: 99%

“…[ 30 ] In another study, a polymer blend of carboxymethyl cellulose (CMC) and gum arabic was used for the adsorption of basic as well as acidic dyes. [ 67 ]…”

Section: Gum Arabicmentioning

confidence: 99%

Recent Progress on the Design and Applications of Polysaccharide‐Based Graft Copolymer Hydrogels as Adsorbents for Wastewater Purification

Mittal

Ray

Okamoto

2016

Macro Materials & Eng

131

View full text Add to dashboard Cite

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“…[34] Recently, particular attention has been paid to producing dye adsorbents from cellulosic polymers due to their advantages of being abundant, rapidly renewable, and biodegradable in nature. [11] The adsorbent products are usually prepared in the form of hydrogels owing to their three-dimensional porous inner structure, readily swelling behavior, and strong adsorption capacity of dyes. Many cellulose derivatives such as carboxymethyl cellulose are utilized for this process.…”

Section: Removal Of Dyesmentioning

confidence: 99%

“…[10,11] The adsorbent products are usually prepared in the form of hydrogels owing to their three-dimensional were provided from lobachemie PVT. lTD, Mumbai, India., (2,4)-dichlorophenoxy acetic acid 98% was provided from lobachemie PVT.…”

Section: Introductionmentioning

confidence: 99%

Radiation-induced grafting of acrylamide and methacrylic acid individually onto carboxymethyl cellulose for removal of hazardous water pollutants

Ghaffar

El‐Arnaouty

Baky

et al. 2016

Designed Monomers and Polymers

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Carboxymethyl cellulose hydrogels were synthesized by grafting of acrylamide (AAm) and methacrylic acid (MAAc) individually with different concentrations onto carboxymethyl cellulose (CMC) using direct radiation grafting technique. It was found that for both Poly(CMC/AAm) and Poly(CMC/MAAc), the grafting yield and grafting ratio increase with the increasing monomer concentration. Also, it is noted that both grafting ratio and grafting yield of Poly(CMC/AAm) are higher than that of Poly(CMC/MAAc). The effect of different monomer concentrations on gel (%) and swelling behavior was studied. It is found that the increasing monomer concentration increases gel (%). For Poly(CMC/AAm) hydrogels, the swelling behavior decreases with increasing AAm concentration due to high crosslinking hydrogel formation, while as MAAc content increases, swelling behavior increases up to Poly(CMC/MAAc) 1:25 wt%. Swelling kinetics and diffusion mechanism indicate that the water penetration obeys non-Fickian transport mechanism. The structures and properties of the original CMC and the prepared Poly(CMC/MAAc) and Poly(CMC/AAm) were characterized using different analytical tools such as Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and scanning electron microscope (SEM). This study provides a solution to the discharge of different pollutants from wastewater. The adsorption capacity of Poly(CMC/MAAc) and Poly(CMC/AAm) hydrogels toward heavy metals, Cu +2 and Co +2, dyes such as acid blue dye and methyl green, and organic contaminants such as 4-chlorophenol and 2,4-Dichlorophenoxy acetic acid has been investigated.

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“…Carboxymethyl Cellulose (CMC) is one of the most popular cellulose derivative, it is an anionic polymer and also highly water soluble. It is well known as a safe and biodegradable polymer which is widely used in the food industries as food additives, oil and gas industries, paper and textile industries e.t.c due to its very high viscosity [10]. CMC is synthesized by reacting cellulose with sodium hydroxide in the presence of sodium chloroacetate.…”

Section: Introductionmentioning

confidence: 99%

Synergistic Study between Gum Arabic and Carboxymethyl Cellulose: Application in Polymer Flooding

Eiroboyi

Ikiensikimama

Oriji

et al. 2019

CJAST

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The oil industry is experiencing a paradigm shift where the use of green chemicals is being encouraged in order to address environmental issues associated with the use of synthetic chemicals and also because of the fact that most of these synthetic polymers like hydrolysed polyacrylamide used to improve mobility ratio in Polymer flooding are imported chemicals. Thus, the need to source for other polymers that are viable and equally environmentally friendly. Gum Arabic used in this analysis was obtained from the northern part of Nigeria. Different concentrations of Gum Arabic were analysed to study their rheology as well as the effect of salinity on them in order to determine their degree of resistance for this is a criterion in polymer flooding. However, the stability of Gum Arabic was further enhanced by the addition of Carboxymethyl Cellulose (CMC) at varying concentration to determine its effect on the solution viscosity. Based on the results, the effect of blending resulted in synergistic viscosity however, the stability of the solution with respect to the effect of salinity was affected. Eiroboyi et al.; CJAST, 36(4): 1-7, 2019; Article no.CJAST.49744 2 Original Research Article

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Characterization of Gamma Irradiated Plasticized Carboxymethyl Cellulose (CMC)/Gum Arabic (GA) Polymer Blends as Absorbents for Dyestuffs

Cited by 8 publications

References 10 publications

Recent Progress on the Design and Applications of Polysaccharide‐Based Graft Copolymer Hydrogels as Adsorbents for Wastewater Purification

Recent Progress on the Design and Applications of Polysaccharide‐Based Graft Copolymer Hydrogels as Adsorbents for Wastewater Purification

Radiation-induced grafting of acrylamide and methacrylic acid individually onto carboxymethyl cellulose for removal of hazardous water pollutants

Synergistic Study between Gum Arabic and Carboxymethyl Cellulose: Application in Polymer Flooding

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