Characterization of the oxides formed at 1000°C on the AISI 304 stainless steel by X-ray diffraction and infrared spectroscopy

Karimi, Nader; Riffard, F.; Rabaste, Françoise; Perrier, S.; Cueff, R.; Issartel, Christophe; Buscail, Henri

doi:10.1016/j.apsusc.2007.09.018

Cited by 83 publications

(44 citation statements)

References 36 publications

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“…After dieless drawing forming, the surface of AISI304 stainless steel tapered pipes was oxidized with generating dark brown oxide, that contains mainly FeO, Fe 2 O 3 , Fe 3 O 4 , and FeCr 2 O 4 [7,8], as shown in Figure 2.…”

Section: Resultsmentioning

confidence: 99%

“…An oxidation film with uniform thickness forms on the metal surface, and the oxidation kinetics curve obeys a linear law, or a parabolic law, or other laws when the metal is heated in a constant temperature and pressure environment [6][7][8][9][10]. As the metal matrix suffered elastic deformation or creep induced by a tensile stress, the surface oxidation film was prone to cracking and brittle rupture because of its worse plasticity, and then oxidation resistance deteriorated and the growth of oxide film was accelerated, thus the oxidation rate was affected severely by stress and deformation of metal [5,[11][12][13].…”

Section: Introductionmentioning

confidence: 99%

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The Thickness Distribution of Oxidation Film on Tapered Pipe Surface in Dieless Drawing

Qin

Liu

Hao-en

2011

International Journal of Corrosion

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The thickness distribution of oxidation film on the surface of AISI304 stainless steel tapered pipe, its influence factors, and the effect of metal matrix deformation on oxidation behavior during dieless drawing were studied in this paper. The results showed that oxidation rate was affected strongly by induction heating temperature and deformation degree. The thickness distribution of oxidation film was uneven and increased from the larger diameter end to the smaller diameter end along the axial direction of tapered pipe. When induction heating temperature raised or the distance between heat and cold sources was increased, or feed speed was decreased, oxidation rate was accelerated and oxidation film on the tapered pipe surface thickened significantly, due to massive cracks in oxidation film induced by deformation of metal matrix. The density and width of cracks in oxidation film were enlarged, and the thickness of oxidation film increased with the increase in deformation degree.

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Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

The Thickness Distribution of Oxidation Film on Tapered Pipe Surface in Dieless Drawing

Qin

Liu

Hao-en

2011

International Journal of Corrosion

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“…The experimental results of k p falls inside k c calculated values of the hematite, spinel, and chromia, confirming that all different oxides contribute to the oxidation. However, according to the general models of the oxidation [1][2][3][4][5], the contributions of the single oxides are not constant during the annealing, and thus it is not possible to separate them only from the values of the parabolic constants. …”

Section: Growth Modelmentioning

confidence: 99%

“…Several models for the oxide growth on stainless steels are present in the literature [1][2][3][4][5]. They can be summarized considering the formation of a chromia (Cr 2 O 3 ) layer at low temperatures, which acts as a protective barrier against further oxidation.…”

Section: Introductionmentioning

confidence: 99%

Thermodynamic and Kinetics Aspects of High Temperature Oxidation on a 304L Stainless Steel

et al. 2013

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“…Some authors consider 1,023 K to be a suitable temperature to obtain optimum performance in this type of stainless steel [25] . The oxidation in air at 1,273 K shows that the scale formed is composed of two subscales; internal adherent and external spalled subscales, chromia appears to be slightly present in the adherent subscale and two spinels Mn 1.5 Cr 1.5 O 4 and FeCr 2 O 4 as well as hematite Fe 2 O 3 in the external spalled subscale [26] .…”

Section: Introductionmentioning

confidence: 99%

Oxidation behaviour at 1123 K of AISI 304-Ni/Al-Al2O3/TiO2 multilayer system deposited by flame spray

Habib¹,

Saura²,

Ferrer³

et al. 2011

REVMETAL

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The oxidation behaviour of alumina/titania (97/3, 87/13 and 60/40) ceramic coatings using a Ni-Al coupling layer was studied in a thermobalance. Both layers were deposited on an AISI 304 stainless steel base metal by the flame spray technique. The coated steel was heated from room temperature to 1,123 K at 40 K min -1 , oxidized in air for 50 h, and then cooled to room temperature at 40 K min -1 . The mass gain was mainly attributed to the oxidation of Ni-Al coupling layer. Kinetic laws, DW·S -1 (mg.mm -2 ) vs. time (hours) were close to a parabolic plot for each sample. Surface composition of ceramic top layer and the cross section of multilayer system were analysed using a wide range of experimental techniques including Scanning Electron Microscopy (SEM), equipped with a link energy dispersive X-Ray spectroscopy (EDX) and X-Ray diffraction (XRD) before and after the oxidation process. Coatings 97/3 and 87/13 presented a stable structure after flame spray deposition and they did not evolve with the oxidation process, while most of the 60/40 coating changed to a metastable structure after deposition and to a more stable structure after oxidation with high micro-cracks content. SEM and EDX microanalysis of the cross-sections showed that significant oxidation and a weak intergranular precipitation had been produced in the coupling layer and on the stainless steel base metal, respectively. ResumenEl comportamiento a oxidación de recubrimientos cerámicos alúmina/titania (97/3, 87/13, 60/40) usando una capa de anclaje Ni-Al se ha estudiado mediante una termobalanza. Ambas capas se han depositado sobre un acero inoxidable AISI 304 utilizando la técnica de proyección llama (FS). El acero recubierto se ha calentado desde la temperatura ambiente hasta 1.123 K a 40 K min -1 , se ha oxidado al aire durante 50 h, y luego se ha enfriado hasta la temperatura ambiente a 40 K min -1 . La ganancia en masa se atribuye a la oxidación de la capa de enganche Ni-Al. La cinética DW·S -1 (mg.mm -2 ) vs. tiempo (horas) se ha ajustado a una ley parabólica para todas las muestras. La composición superficial de la capa cerámica y la sección transversal del sistema multicapa se han analizado mediante las técnicas de Microscopía Electrónica de Barrido (SEM), Espectroscopia de Energías Dispersivas de Rayos X (EDX), Difracción de Rayos X (XRD) antes y después del proceso de oxidación. Los recubrimientos 97/3 y 87/13 han presentado una estructura estable tras el proceso de deposición por proyección por llama y esta estructura tampoco ha evolucionado después de la oxidación, mientras la mayor parte del recubrimiento 60/40 ha cambiado a una estructura metaestable después la deposición y finalmente ha evolucionado a una estructura más estable después de la oxidación con alto contenido de microagrietamiento. El microanálisis mediante SEM y EDX de las secciones transversales han mostrado una oxidación significativa en la capa de enganche y una débil precipitación intergranular en el material base AISI 304. Palabras claveAISI 304; Capa de an...

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Characterization of the oxides formed at 1000°C on the AISI 304 stainless steel by X-ray diffraction and infrared spectroscopy

Cited by 83 publications

References 36 publications

The Thickness Distribution of Oxidation Film on Tapered Pipe Surface in Dieless Drawing

The Thickness Distribution of Oxidation Film on Tapered Pipe Surface in Dieless Drawing

Thermodynamic and Kinetics Aspects of High Temperature Oxidation on a 304L Stainless Steel

Oxidation behaviour at 1123 K of AISI 304-Ni/Al-Al<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> multilayer system deposited by flame spray

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